Adhesion improvement via surface functionalization of epoxy-resin base post by low temperature plasma
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. The adhesion between dental materials could be improved by an increase of interfacial polarity. In this study, low temperature plasma was used to treat an epoxy-based post. The surface modifications after treatment were characterized by X-ray...
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| Main Authors: | , , , , |
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| Format: | Journal |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84940121413&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/44834 |
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| Institution: | Chiang Mai University |
| Summary: | © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. The adhesion between dental materials could be improved by an increase of interfacial polarity. In this study, low temperature plasma was used to treat an epoxy-based post. The surface modifications after treatment were characterized by X-ray photoelectron spectroscopy (XPS) which showed the existence of N, O- containing groups in the epoxy-based post. Furthermore, functionalization positions were proposed by Quantum Mechanic (QM) calculation. It could confirm the position that such a functional group was formed at hydroxyl group and alpha-carbon with an energy level around 93-97 kcal/mol through hydrogen abstraction reaction. Both experiments and calculations show consistent results indicating polar group formation on the surface after plasma treatments. |
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