Imidazolium cation transportation in a 1-D coordination polymer
© 2017 The Royal Society of Chemistry. We synthesized a coordination polymer, [EtMeIm][Cu(bpy)(Me 2 PO 4 ) 3 ], containing an anionic 1-D chain and an ethyl methyl imidazolium cation. The organic cations show fast transport behavior, and the observed ion conductivity is 1.4 × 10 -3 S cm -1 at 110 °C...
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| Main Authors: | , , , , , |
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| Format: | Journal |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85028060178&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/46609 |
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| Institution: | Chiang Mai University |
| Summary: | © 2017 The Royal Society of Chemistry. We synthesized a coordination polymer, [EtMeIm][Cu(bpy)(Me 2 PO 4 ) 3 ], containing an anionic 1-D chain and an ethyl methyl imidazolium cation. The organic cations show fast transport behavior, and the observed ion conductivity is 1.4 × 10 -3 S cm -1 at 110 °C. The stability and structure of the material were confirmed by DSC, X-ray adsorption, and long-term AC impedance spectroscopy. |
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