Synthesis of copolymer thieno[3,4-b]thiophene and benzodithiophene for application in solar cells

Synthesis of copolymer thieno[3,4-b]thiophene and benzodithiophene for application in solar cells

Synthesis of poly(2-hexylthieno[3,4-b]thiophene-co-4,8-didodecyloxybenzo[1, 2-b:4, 5-b-] dithiophene) (PTB) is presented using a simple and low cost method. Anhydrous DMF and toluene was added into the mixture of 4,6-dibromo-2- hexylthieno[3,4-b] thiophene,2,6-Bis(trimethyltin)-4,8-didodecyloxybenzo...

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Main Authors: C. Khantha, T. Yakhanthip, C. M. Macneill, P. Pornprasit, V. Kruefu, N. Kungwan, R. C. Coffin, S. Phanichphant, D. L. Carroll
Format: Journal
Published: 2018
Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84884522408&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/47636
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Institution: Chiang Mai University
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spelling th-cmuir.6653943832-476362018-04-25T08:42:15Z Synthesis of copolymer thieno[3,4-b]thiophene and benzodithiophene for application in solar cells C. Khantha T. Yakhanthip C. M. Macneill P. Pornprasit V. Kruefu N. Kungwan R. C. Coffin S. Phanichphant D. L. Carroll Synthesis of poly(2-hexylthieno[3,4-b]thiophene-co-4,8-didodecyloxybenzo[1, 2-b:4, 5-b-] dithiophene) (PTB) is presented using a simple and low cost method. Anhydrous DMF and toluene was added into the mixture of 4,6-dibromo-2- hexylthieno[3,4-b] thiophene,2,6-Bis(trimethyltin)-4,8-didodecyloxybenzo[1,2-b: 4,5-b-] dithiophene and Pd(PPh3)4. The polymerization was carried out at 120?C for 12 h. The PTB product was precipitated in methanol and dried in vacuum. The HOMO and LUMO energies of the polymer were calculated using Density Functional Theory (DFT) calculations to be compared with the experimental results. Copyright © Taylor & Francis Group, LLC. 2018-04-25T08:42:15Z 2018-04-25T08:42:15Z 2013-09-27 Journal 15635287 15421406 2-s2.0-84884522408 10.1080/15421406.2013.803430 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84884522408&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/47636
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
description Synthesis of poly(2-hexylthieno[3,4-b]thiophene-co-4,8-didodecyloxybenzo[1, 2-b:4, 5-b-] dithiophene) (PTB) is presented using a simple and low cost method. Anhydrous DMF and toluene was added into the mixture of 4,6-dibromo-2- hexylthieno[3,4-b] thiophene,2,6-Bis(trimethyltin)-4,8-didodecyloxybenzo[1,2-b: 4,5-b-] dithiophene and Pd(PPh3)4. The polymerization was carried out at 120?C for 12 h. The PTB product was precipitated in methanol and dried in vacuum. The HOMO and LUMO energies of the polymer were calculated using Density Functional Theory (DFT) calculations to be compared with the experimental results. Copyright © Taylor & Francis Group, LLC.
format Journal
author C. Khantha
T. Yakhanthip
C. M. Macneill
P. Pornprasit
V. Kruefu
N. Kungwan
R. C. Coffin
S. Phanichphant
D. L. Carroll
spellingShingle C. Khantha
T. Yakhanthip
C. M. Macneill
P. Pornprasit
V. Kruefu
N. Kungwan
R. C. Coffin
S. Phanichphant
D. L. Carroll
Synthesis of copolymer thieno[3,4-b]thiophene and benzodithiophene for application in solar cells
author_facet C. Khantha
T. Yakhanthip
C. M. Macneill
P. Pornprasit
V. Kruefu
N. Kungwan
R. C. Coffin
S. Phanichphant
D. L. Carroll
author_sort C. Khantha
title Synthesis of copolymer thieno[3,4-b]thiophene and benzodithiophene for application in solar cells
title_short Synthesis of copolymer thieno[3,4-b]thiophene and benzodithiophene for application in solar cells
title_full Synthesis of copolymer thieno[3,4-b]thiophene and benzodithiophene for application in solar cells
title_fullStr Synthesis of copolymer thieno[3,4-b]thiophene and benzodithiophene for application in solar cells
title_full_unstemmed Synthesis of copolymer thieno[3,4-b]thiophene and benzodithiophene for application in solar cells
title_sort synthesis of copolymer thieno[3,4-b]thiophene and benzodithiophene for application in solar cells
publishDate 2018
url https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84884522408&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/47636
_version_ 1681423098487767040

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