Hydrogen generation by photocatalytic reforming of potential biofuels: Polyols, cyclic alcohols, and saccharides
© 2018 Elsevier B.V. We have studied hydrogen gas production using photocatalysis from C2-C5 carbon chain polyols, cyclic alcohols and mono and di-saccharides using palladium nanoparticles supported on a TiO 2 catalyst. For many of the polyols the hydrogen evolution rate is found to be dictated by t...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Journal |
| Published: |
2018
|
| Online Access: | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85041641597&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/48430 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Chiang Mai University |
| id |
th-cmuir.6653943832-48430 |
|---|---|
| record_format |
dspace |
| spelling |
th-cmuir.6653943832-484302018-04-25T10:12:21Z Hydrogen generation by photocatalytic reforming of potential biofuels: Polyols, cyclic alcohols, and saccharides Julia Kennedy Hasliza Bahruji Michael Bowker Philip R. Davies Emir Bouleghlimat Sudarat Issarapanacheewin © 2018 Elsevier B.V. We have studied hydrogen gas production using photocatalysis from C2-C5 carbon chain polyols, cyclic alcohols and mono and di-saccharides using palladium nanoparticles supported on a TiO 2 catalyst. For many of the polyols the hydrogen evolution rate is found to be dictated by the number of hydroxyl groups and available α-hydrogens in the structure. However the rule only applies to polyols and cyclic alcohols, while the sugar activity is limited by the bulky structure of those molecules. There was also evidence of ring opening in photocatalytic reforming of cyclic alcohols that involved dehydrogenation and decarbonylation of α C–C bond. 2018-04-25T10:12:21Z 2018-04-25T10:12:21Z 2018-04-01 Journal 10106030 2-s2.0-85041641597 10.1016/j.jphotochem.2018.01.031 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85041641597&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/48430 |
| institution |
Chiang Mai University |
| building |
Chiang Mai University Library |
| country |
Thailand |
| collection |
CMU Intellectual Repository |
| description |
© 2018 Elsevier B.V. We have studied hydrogen gas production using photocatalysis from C2-C5 carbon chain polyols, cyclic alcohols and mono and di-saccharides using palladium nanoparticles supported on a TiO 2 catalyst. For many of the polyols the hydrogen evolution rate is found to be dictated by the number of hydroxyl groups and available α-hydrogens in the structure. However the rule only applies to polyols and cyclic alcohols, while the sugar activity is limited by the bulky structure of those molecules. There was also evidence of ring opening in photocatalytic reforming of cyclic alcohols that involved dehydrogenation and decarbonylation of α C–C bond. |
| format |
Journal |
| author |
Julia Kennedy Hasliza Bahruji Michael Bowker Philip R. Davies Emir Bouleghlimat Sudarat Issarapanacheewin |
| spellingShingle |
Julia Kennedy Hasliza Bahruji Michael Bowker Philip R. Davies Emir Bouleghlimat Sudarat Issarapanacheewin Hydrogen generation by photocatalytic reforming of potential biofuels: Polyols, cyclic alcohols, and saccharides |
| author_facet |
Julia Kennedy Hasliza Bahruji Michael Bowker Philip R. Davies Emir Bouleghlimat Sudarat Issarapanacheewin |
| author_sort |
Julia Kennedy |
| title |
Hydrogen generation by photocatalytic reforming of potential biofuels: Polyols, cyclic alcohols, and saccharides |
| title_short |
Hydrogen generation by photocatalytic reforming of potential biofuels: Polyols, cyclic alcohols, and saccharides |
| title_full |
Hydrogen generation by photocatalytic reforming of potential biofuels: Polyols, cyclic alcohols, and saccharides |
| title_fullStr |
Hydrogen generation by photocatalytic reforming of potential biofuels: Polyols, cyclic alcohols, and saccharides |
| title_full_unstemmed |
Hydrogen generation by photocatalytic reforming of potential biofuels: Polyols, cyclic alcohols, and saccharides |
| title_sort |
hydrogen generation by photocatalytic reforming of potential biofuels: polyols, cyclic alcohols, and saccharides |
| publishDate |
2018 |
| url |
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85041641597&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/48430 |
| _version_ |
1681423247645605888 |