Biodegradable Plasticized Blends of Poly(L-lactide) and Cellulose Acetate Butyrate: From Blend Preparation to Biodegradability in Real Composting Conditions

• Main Authors: Kunthadong P., Molloy R., Worajittiphon P., Leejarkpai T., Kaabbuathong N., Punyodom W.
• Format: Article
• Language: English
• Published: 2014
• Online Access: http://www.scopus.com/inward/record.url?eid=2-s2.0-84902896770&partnerID=40&md5=4166344a3ee66df808c86904da860477; http://cmuir.cmu.ac.th/handle/6653943832/4862
• Institution: Chiang Mai University

Biodegradable blends of poly(L-lactide) (PLL) and cellulose acetate butyrate (CAB) were prepared as 40-60 μm thick films cast from solution using chloroform as a solvent. Both poly(ethylene glycol) (PEG) and a polyester adipate (Paraplex G40) were used as plasticizers to decrease the PLL/CAB blends' glass transition temperature and make them more flexible. Ternary PLL/CAB/PEG blends showed only partial compatibility due to phase separation of crystalline PLL-rich and CAB-rich domains. In contrast, when Paraplex G40 was used as the plasticizer, it produced PLL/CAB/Paraplex G40 blends with stable morphology over an extended period of time with much reduced phase separation. The PLL/CAB/plasticizer blend films all degraded in real composting conditions at PLL contents of over 50 wt%. Moreover, the PEG-plasticized ternary blend films showed complete degradability at PLL ≥ 70 and CAB ≤ 30 wt%. These results suggest that the CAB content and plasticizer type can be used to tune polymer blend compatibility and biodegradability. The most promising formulations were found to be PLL/CAB/Paraplex G40 blends with compositions of PLL ≥ 70, CAB ≤ 30 and Paraplex G40 = 20 parts by weight, combining good polymer compatibility and biodegradability with a suitable balance of mechanical properties. © 2014 Springer Science+Business Media New York.