Dual optical detection of a novel selective mercury sensor based on 7-nitrobenzo-2-oxa-1,3-diazolyl subunits
A novel macromolecule based on 2-[3-(2-aminoethylthio)propylthio]ethanamine covalently bound to two 7-nitrobenzo-2-oxa-1,3-diazolyl moieties was prepared as a fluoroionophore and a chromophore for the selective optical detection of Hg2+. The sensor was prepared in two steps and its fluoroionophoric...
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| Main Authors: | , , , |
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| Format: | Journal |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=61349160485&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/48887 |
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| Institution: | Chiang Mai University |
| Summary: | A novel macromolecule based on 2-[3-(2-aminoethylthio)propylthio]ethanamine covalently bound to two 7-nitrobenzo-2-oxa-1,3-diazolyl moieties was prepared as a fluoroionophore and a chromophore for the selective optical detection of Hg2+. The sensor was prepared in two steps and its fluoroionophoric and chromophoric properties toward various transition metal, alkali, and alkali earth cations were investigated. Compound 4 selectively binds Hg2+, and the binding is indicated by both fluorescence quenching and a chromogenic change which can be detected by the naked eye. In an 80:20 acetonitrile/water solvent mixture, 4 acts as an ON-OFF fluorescence switch upon Hg2+binding, exhibiting efficient quenching and a detection limit of 10-7M or 20 ppb. © 2009 Elsevier Ltd. All rights reserved. |
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