Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic dis...
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2014
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th-cmuir.6653943832-48902014-08-30T02:55:55Z Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation Funfuenha W. Phakhodee W. Pattarawarapan M. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks. © 2014 Elsevier Ltd. All rights reserved. 2014-08-30T02:55:55Z 2014-08-30T02:55:55Z 2014 Article in Press 00404020 10.1016/j.tet.2014.06.127 TETRA http://www.scopus.com/inward/record.url?eid=2-s2.0-84903854342&partnerID=40&md5=f3d289f31cc4a3e3d904d5c9ab9a20a8 http://cmuir.cmu.ac.th/handle/6653943832/4890 English |
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A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks. © 2014 Elsevier Ltd. All rights reserved. |
| format |
Article |
| author |
Funfuenha W. Phakhodee W. Pattarawarapan M. |
| spellingShingle |
Funfuenha W. Phakhodee W. Pattarawarapan M. Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
| author_facet |
Funfuenha W. Phakhodee W. Pattarawarapan M. |
| author_sort |
Funfuenha W. |
| title |
Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
| title_short |
Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
| title_full |
Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
| title_fullStr |
Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
| title_full_unstemmed |
Facile and efficient synthesis of C2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
| title_sort |
facile and efficient synthesis of c2-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
| publishDate |
2014 |
| url |
http://www.scopus.com/inward/record.url?eid=2-s2.0-84903854342&partnerID=40&md5=f3d289f31cc4a3e3d904d5c9ab9a20a8 http://cmuir.cmu.ac.th/handle/6653943832/4890 |
| _version_ |
1681420322179383296 |