Preparation and characterization of bis(μ-1,2-diaminoethane)cobalt(ii) hexavanadate: A layered polyoxovanadate pillared by a cobalt coordination complex

Preparation and characterization of bis(μ-1,2-diaminoethane)cobalt(ii) hexavanadate: A layered polyoxovanadate pillared by a cobalt coordination complex

The first example of polyoxovanadate layered framework with a cobalt coordination complex as a pillaring unit, CoII(μ-C2N2H8)2[V4IVV2VO14], was readily synthesized under hydrothermal conditions. The structure can be solved and refined in monoclinic P21/n with a = 9.143(3) Å, b = 6.5034(11) Å, c = 15...

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Main Authors: Bunlawee Yotnoi, Jumras Limtrakul, Timothy Prior, Apinpus Rujiwatra
Format: Journal
Published: 2018
Subjects:
Chemistry
Physics and Astronomy
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http://cmuir.cmu.ac.th/jspui/handle/6653943832/48977
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Institution: Chiang Mai University
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spelling th-cmuir.6653943832-489772018-08-16T02:18:03Z Preparation and characterization of bis(μ-1,2-diaminoethane)cobalt(ii) hexavanadate: A layered polyoxovanadate pillared by a cobalt coordination complex Bunlawee Yotnoi Jumras Limtrakul Timothy Prior Apinpus Rujiwatra Chemistry Physics and Astronomy The first example of polyoxovanadate layered framework with a cobalt coordination complex as a pillaring unit, CoII(μ-C2N2H8)2[V4IVV2VO14], was readily synthesized under hydrothermal conditions. The structure can be solved and refined in monoclinic P21/n with a = 9.143(3) Å, b = 6.5034(11) Å, c = 15.874(4) Å, β = 101.90(2), V = 923.6(4) Å3and Z = 2. The crystal structure comprises two-dimensional {V4IVV2VO14}2-layers extending parallel to [101], constructed from tetrahedral {VVO4} and square pyramidal {VIVO5} building units. Adjacent layers are linked through the octahedral {CoIIO2(μ-C2N2H8)2} pillars, within which the CoIIresides on an inversion center. The structure displays N-H•••O and C-H•••O hydrogen bonding between the ethylenediamine and vanadium oxide layers. © 2009 Springer Science+Business Media, LLC. 2018-08-16T02:07:34Z 2018-08-16T02:07:34Z 2009-07-01 Journal 10741542 2-s2.0-67349216835 10.1007/s10870-009-9529-9 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=67349216835&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/48977
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
topic Chemistry
Physics and Astronomy
spellingShingle Chemistry
Physics and Astronomy
Bunlawee Yotnoi
Jumras Limtrakul
Timothy Prior
Apinpus Rujiwatra
Preparation and characterization of bis(μ-1,2-diaminoethane)cobalt(ii) hexavanadate: A layered polyoxovanadate pillared by a cobalt coordination complex
description The first example of polyoxovanadate layered framework with a cobalt coordination complex as a pillaring unit, CoII(μ-C2N2H8)2[V4IVV2VO14], was readily synthesized under hydrothermal conditions. The structure can be solved and refined in monoclinic P21/n with a = 9.143(3) Å, b = 6.5034(11) Å, c = 15.874(4) Å, β = 101.90(2), V = 923.6(4) Å3and Z = 2. The crystal structure comprises two-dimensional {V4IVV2VO14}2-layers extending parallel to [101], constructed from tetrahedral {VVO4} and square pyramidal {VIVO5} building units. Adjacent layers are linked through the octahedral {CoIIO2(μ-C2N2H8)2} pillars, within which the CoIIresides on an inversion center. The structure displays N-H•••O and C-H•••O hydrogen bonding between the ethylenediamine and vanadium oxide layers. © 2009 Springer Science+Business Media, LLC.
format Journal
author Bunlawee Yotnoi
Jumras Limtrakul
Timothy Prior
Apinpus Rujiwatra
author_facet Bunlawee Yotnoi
Jumras Limtrakul
Timothy Prior
Apinpus Rujiwatra
author_sort Bunlawee Yotnoi
title Preparation and characterization of bis(μ-1,2-diaminoethane)cobalt(ii) hexavanadate: A layered polyoxovanadate pillared by a cobalt coordination complex
title_short Preparation and characterization of bis(μ-1,2-diaminoethane)cobalt(ii) hexavanadate: A layered polyoxovanadate pillared by a cobalt coordination complex
title_full Preparation and characterization of bis(μ-1,2-diaminoethane)cobalt(ii) hexavanadate: A layered polyoxovanadate pillared by a cobalt coordination complex
title_fullStr Preparation and characterization of bis(μ-1,2-diaminoethane)cobalt(ii) hexavanadate: A layered polyoxovanadate pillared by a cobalt coordination complex
title_full_unstemmed Preparation and characterization of bis(μ-1,2-diaminoethane)cobalt(ii) hexavanadate: A layered polyoxovanadate pillared by a cobalt coordination complex
title_sort preparation and characterization of bis(μ-1,2-diaminoethane)cobalt(ii) hexavanadate: a layered polyoxovanadate pillared by a cobalt coordination complex
publishDate 2018
url https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=67349216835&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/48977
_version_ 1681423327220989952

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