Effect of excess PbO on phase formation and properties of (Pb 0.90Ba0.10)ZrO3 ceramics
Polycrystalline samples of (Pb0.90Ba0.10)ZrO 3 (PBZ) were prepared by a mixed oxide, solid-state reaction method. Excess PbO (3, 5 or 10 wt.%) was introduced prior to powder calcination to compensate for any PbO that may have been lost from the samples due to volatilisation during heat treatments. X...
Saved in:
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
2014
|
Online Access: | http://www.scopus.com/inward/record.url?eid=2-s2.0-14644444586&partnerID=40&md5=88e53c612f8f3c251e64a0aa98c168ef http://cmuir.cmu.ac.th/handle/6653943832/4997 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Chiang Mai University |
Language: | English |
id |
th-cmuir.6653943832-4997 |
---|---|
record_format |
dspace |
spelling |
th-cmuir.6653943832-49972014-08-30T02:56:02Z Effect of excess PbO on phase formation and properties of (Pb 0.90Ba0.10)ZrO3 ceramics Bongkarn T. Rujijanagul G. Milne S.J. Polycrystalline samples of (Pb0.90Ba0.10)ZrO 3 (PBZ) were prepared by a mixed oxide, solid-state reaction method. Excess PbO (3, 5 or 10 wt.%) was introduced prior to powder calcination to compensate for any PbO that may have been lost from the samples due to volatilisation during heat treatments. X-ray diffraction revealed that, compared to samples made from stoichiometric starting mixtures, a starting excess of PbO of ≥ wt.% increased the proportion of the rhombohedral PBZ phase which coexisted with the antiferroelectric orthorhombic phase. Microstructurally, excess PbO produced an increase in average grain size, from ∼1 μm for no excess to ~1.5 μm for ≥3 wt.% excess PbO. The fractured surfaces indicated predominantly intra-granular fracture in samples with no added PbO, or 3 wt.% excess PbO, whereas the 5 and 10 wt.% excess PbO samples displayed mainly inter-granular fracture. Dielectric constant-temperature plots showed a maximum peak value of 12,700 for the 3 wt.% sample which was also the most dense sample. © 2005 Elsevier B.V. All rights reserved. 2014-08-30T02:56:02Z 2014-08-30T02:56:02Z 2005 Article 0167577X 10.1016/j.matlet.2004.12.028 MLETD http://www.scopus.com/inward/record.url?eid=2-s2.0-14644444586&partnerID=40&md5=88e53c612f8f3c251e64a0aa98c168ef http://cmuir.cmu.ac.th/handle/6653943832/4997 English |
institution |
Chiang Mai University |
building |
Chiang Mai University Library |
country |
Thailand |
collection |
CMU Intellectual Repository |
language |
English |
description |
Polycrystalline samples of (Pb0.90Ba0.10)ZrO 3 (PBZ) were prepared by a mixed oxide, solid-state reaction method. Excess PbO (3, 5 or 10 wt.%) was introduced prior to powder calcination to compensate for any PbO that may have been lost from the samples due to volatilisation during heat treatments. X-ray diffraction revealed that, compared to samples made from stoichiometric starting mixtures, a starting excess of PbO of ≥ wt.% increased the proportion of the rhombohedral PBZ phase which coexisted with the antiferroelectric orthorhombic phase. Microstructurally, excess PbO produced an increase in average grain size, from ∼1 μm for no excess to ~1.5 μm for ≥3 wt.% excess PbO. The fractured surfaces indicated predominantly intra-granular fracture in samples with no added PbO, or 3 wt.% excess PbO, whereas the 5 and 10 wt.% excess PbO samples displayed mainly inter-granular fracture. Dielectric constant-temperature plots showed a maximum peak value of 12,700 for the 3 wt.% sample which was also the most dense sample. © 2005 Elsevier B.V. All rights reserved. |
format |
Article |
author |
Bongkarn T. Rujijanagul G. Milne S.J. |
spellingShingle |
Bongkarn T. Rujijanagul G. Milne S.J. Effect of excess PbO on phase formation and properties of (Pb 0.90Ba0.10)ZrO3 ceramics |
author_facet |
Bongkarn T. Rujijanagul G. Milne S.J. |
author_sort |
Bongkarn T. |
title |
Effect of excess PbO on phase formation and properties of (Pb 0.90Ba0.10)ZrO3 ceramics |
title_short |
Effect of excess PbO on phase formation and properties of (Pb 0.90Ba0.10)ZrO3 ceramics |
title_full |
Effect of excess PbO on phase formation and properties of (Pb 0.90Ba0.10)ZrO3 ceramics |
title_fullStr |
Effect of excess PbO on phase formation and properties of (Pb 0.90Ba0.10)ZrO3 ceramics |
title_full_unstemmed |
Effect of excess PbO on phase formation and properties of (Pb 0.90Ba0.10)ZrO3 ceramics |
title_sort |
effect of excess pbo on phase formation and properties of (pb 0.90ba0.10)zro3 ceramics |
publishDate |
2014 |
url |
http://www.scopus.com/inward/record.url?eid=2-s2.0-14644444586&partnerID=40&md5=88e53c612f8f3c251e64a0aa98c168ef http://cmuir.cmu.ac.th/handle/6653943832/4997 |
_version_ |
1681420342153707520 |