Effect of high roughness on a long aging time of superhydrophilic TiO 2 nanoparticle thin films
TiO2nanoparticle thin films with a high roughness were successfully deposited on quartz substrates by a sparking process. To obtain a uniform film thickness, the substrate was moved raster-like across an area of 1 × 1 cm2by the x-y scanning stage. Effects of annealing temperatures on surface morphol...
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th-cmuir.6653943832-500642018-09-04T04:29:45Z Effect of high roughness on a long aging time of superhydrophilic TiO 2 nanoparticle thin films W. Thongsuwan T. Kumpika P. Singjai Materials Science Physics and Astronomy TiO2nanoparticle thin films with a high roughness were successfully deposited on quartz substrates by a sparking process. To obtain a uniform film thickness, the substrate was moved raster-like across an area of 1 × 1 cm2by the x-y scanning stage. Effects of annealing temperatures on surface morphology, chemical structure, photocatalytic and wetting properties were examined by scanning and transmission electron microscopy, atomic force microscopy, Raman spectroscopy, UV-vis spectroscopy and contact angle measurement, respectively. The sample annealed at the optimum temperature of 500 °C shows the highest RMS roughness, photocatalytic activity and also the lowest water contact angle. An optimum anatase/rutile ratio and maximum RMS roughness were believed to be the reason for the above results. In contrast with most previous reports, the films prepared by this process remain highly superhydrophilic after 5 weeks without UV exposure. © 2011 Elsevier B.V. All rights reserved. 2018-09-04T04:23:11Z 2018-09-04T04:23:11Z 2011-09-01 Journal 15671739 2-s2.0-79959774486 10.1016/j.cap.2011.03.002 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=79959774486&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/50064 |
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Materials Science Physics and Astronomy W. Thongsuwan T. Kumpika P. Singjai Effect of high roughness on a long aging time of superhydrophilic TiO 2 nanoparticle thin films |
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TiO2nanoparticle thin films with a high roughness were successfully deposited on quartz substrates by a sparking process. To obtain a uniform film thickness, the substrate was moved raster-like across an area of 1 × 1 cm2by the x-y scanning stage. Effects of annealing temperatures on surface morphology, chemical structure, photocatalytic and wetting properties were examined by scanning and transmission electron microscopy, atomic force microscopy, Raman spectroscopy, UV-vis spectroscopy and contact angle measurement, respectively. The sample annealed at the optimum temperature of 500 °C shows the highest RMS roughness, photocatalytic activity and also the lowest water contact angle. An optimum anatase/rutile ratio and maximum RMS roughness were believed to be the reason for the above results. In contrast with most previous reports, the films prepared by this process remain highly superhydrophilic after 5 weeks without UV exposure. © 2011 Elsevier B.V. All rights reserved. |
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author |
W. Thongsuwan T. Kumpika P. Singjai |
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W. Thongsuwan T. Kumpika P. Singjai |
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W. Thongsuwan |
title |
Effect of high roughness on a long aging time of superhydrophilic TiO 2 nanoparticle thin films |
title_short |
Effect of high roughness on a long aging time of superhydrophilic TiO 2 nanoparticle thin films |
title_full |
Effect of high roughness on a long aging time of superhydrophilic TiO 2 nanoparticle thin films |
title_fullStr |
Effect of high roughness on a long aging time of superhydrophilic TiO 2 nanoparticle thin films |
title_full_unstemmed |
Effect of high roughness on a long aging time of superhydrophilic TiO 2 nanoparticle thin films |
title_sort |
effect of high roughness on a long aging time of superhydrophilic tio 2 nanoparticle thin films |
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2018 |
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https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=79959774486&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/50064 |
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