Rhodamine B-based turn-on fluorescent and colorimetric chemosensors for highly sensitive and selective detection of mercury (II) ions

• Main Authors: Nantanit Wanichacheva, Krit Setthakarn, Narupon Prapawattanapol, Oranual Hanmeng, Vannajan Sanghiran Lee, Kate Grudpan
• Format: Journal
• Published: 2018
• Subjects: Biochemistry, Genetics and Molecular Biology; Chemistry; Physics and Astronomy
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=79961122857&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/51430
• Institution: Chiang Mai University

Two novel macromolecules based on 2-[3-(2-aminoethylsulfanyl) propylsulfanyl]ethanamine covalently bound to one and two units of rhodamine-B moieties, 1 and 2, were prepared and utilized as fluoroionophores and chromophores for the optical detection of Hg2ions. The sensors were readily prepared by a conventional two-step synthesis. Especially, sensor 1 exhibits high sensitivity and selective OFFON fluorescence enhancement and chromogenic change upon binding to Hg2, which served as a naked-eye indicator by a noticeable color change of the solution (from colorless to pinkred color). 1 is shown to discriminate various competing metal ions, particularly Ag and Cu2, as well as Cd2, Na, Li, K, Ba2, Co2, Ni2, Mg2, Mn2and Al3, with a detection limit of 10 ppb. © 2011 Elsevier B.V. All rights reserved.