Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films

Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films

The synthesis, layer-by-layer deposition, and electro-copolymerization of precursor polyelectrolyte multilayer ultrathin films with thiophene and carbazole electroactive groups are described. The interest is in observing an electrochemical cross-linking approach towards a highly ordered ultrathin fi...

Full description

Saved in:
Bibliographic Details
Main Authors: Waenkaew P., Taranekar P., Phanichphant S., Advincula R.C.
Format: Article
Language:English
Published: 2014
Online Access:http://www.scopus.com/inward/record.url?eid=2-s2.0-34548020290&partnerID=40&md5=c99947f3babb75a5663457216c80a83b
http://cmuir.cmu.ac.th/handle/6653943832/5223
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Chiang Mai University
Language: English
id th-cmuir.6653943832-5223
record_format dspace
spelling th-cmuir.6653943832-52232014-08-30T02:56:17Z Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films Waenkaew P. Taranekar P. Phanichphant S. Advincula R.C. The synthesis, layer-by-layer deposition, and electro-copolymerization of precursor polyelectrolyte multilayer ultrathin films with thiophene and carbazole electroactive groups are described. The interest is in observing an electrochemical cross-linking approach towards a highly ordered ultrathin film that contains two types of monomers to result in possible layer-limited homo-and copolymerization. A uniform linear growth with alternate deposition of the polyelectrolytes is observed. The multilayer films were then electrochemically polymerized anodically by cyclic voltammetry (CV), which results in copolymerization between two different electroactive groups. Cross-linking of the layers was verified by CV and spectroelectrochemistry data with very good linear electro-copolymerizability. © 2007 WILEY-VCH Verlag GmbH & Co. KGaA. 2014-08-30T02:56:17Z 2014-08-30T02:56:17Z 2007 Article 10221336 10.1002/marc.200700217 MRCOE http://www.scopus.com/inward/record.url?eid=2-s2.0-34548020290&partnerID=40&md5=c99947f3babb75a5663457216c80a83b http://cmuir.cmu.ac.th/handle/6653943832/5223 English
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
language English
description The synthesis, layer-by-layer deposition, and electro-copolymerization of precursor polyelectrolyte multilayer ultrathin films with thiophene and carbazole electroactive groups are described. The interest is in observing an electrochemical cross-linking approach towards a highly ordered ultrathin film that contains two types of monomers to result in possible layer-limited homo-and copolymerization. A uniform linear growth with alternate deposition of the polyelectrolytes is observed. The multilayer films were then electrochemically polymerized anodically by cyclic voltammetry (CV), which results in copolymerization between two different electroactive groups. Cross-linking of the layers was verified by CV and spectroelectrochemistry data with very good linear electro-copolymerizability. © 2007 WILEY-VCH Verlag GmbH & Co. KGaA.
format Article
author Waenkaew P.
Taranekar P.
Phanichphant S.
Advincula R.C.
spellingShingle Waenkaew P.
Taranekar P.
Phanichphant S.
Advincula R.C.
Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
author_facet Waenkaew P.
Taranekar P.
Phanichphant S.
Advincula R.C.
author_sort Waenkaew P.
title Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
title_short Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
title_full Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
title_fullStr Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
title_full_unstemmed Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
title_sort electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
publishDate 2014
url http://www.scopus.com/inward/record.url?eid=2-s2.0-34548020290&partnerID=40&md5=c99947f3babb75a5663457216c80a83b
http://cmuir.cmu.ac.th/handle/6653943832/5223
_version_ 1681420384697581568

Similar Items