Bis(1,10-phenanthroline-κ² N,N′)(sulfato-κO) copper(II) ethanol monosolvate

• Main Authors: Natthaya Meundaeng, Timothy J. Prior, Apinpus Rujiwatra
• Format: Journal
• Published: 2018
• Subjects: Chemistry; Materials Science; Physics and Astronomy
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84885109176&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/52372
• Institution: Chiang Mai University

The crystal structure of the title compound, [Cu(SO4)(C12H8N2)2] ·C2H5OH, arises from the assembly of the neutral complex [Cu(SO4)(C12H8N2)2] and an ethanol solvent molecule. The CuII ion is five-coordinate, surrounded by two pairs of N atoms from two independent N,N′-chelating 1,10-phenanthroline ligands, and one O atom of monodentate sulfate ligand, in a distorted trigonal-bipyramidal fashion. Spatial orientation of the ligands and the assembly in the solid state are stabilized by the C - H⋯O hydrogen-bonding interactions, established between the O atoms (from the sulfate ligand and the ethanol molecule) and the neighbouring 1,10-phenanthroline molecules. There is also an offset face-to-face π-π stacking between the 1,10-phenanthroline ligands. The ethanol solvent molecule is disordered over two orientations in the ratio 0.663 (10):0.337 (10). The crystal examined was subject to racemic twinning and the refined twin fraction was 0.346 (19).