Upconversion luminescence study of Er<sup>3+</sup>in Gadolinium-Calcium-Silicoborate glasses

The new glass series were prepared in compositions 25Gd2O3-10CaO-10SiO2-(55-x) B2O3-xEr2O3(where x is 0.0, 0.5, 1.0, 1.5, 2.0 and 2.5 mol %) by normal melt-quenching technique at the melting temperature of 1,400 °C. The optical spectra were measured and shown absorption bands were assigned to approp...

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Bibliographic Details
Main Authors: Jakrapong Kaewkhao, Hong Joo Kim, Smit Insiripong, Natthakridta Chanthima, Siriprapa Kaewjaeng, Utumma Maghanemi
Format: Book Series
Published: 2018
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Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84884967677&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/52539
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Institution: Chiang Mai University
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Summary:The new glass series were prepared in compositions 25Gd2O3-10CaO-10SiO2-(55-x) B2O3-xEr2O3(where x is 0.0, 0.5, 1.0, 1.5, 2.0 and 2.5 mol %) by normal melt-quenching technique at the melting temperature of 1,400 °C. The optical spectra were measured and shown absorption bands were assigned to appropriate f-f electronic transitions of Er3+ions from the4I15/2ground state to the following excited states:4G11/2,2H9/2,45/2,4F7/2,2H11/2,4S3/2,4F9/2,4I9/2and4I11/2. Single peak from upconversion luminescence was observed at 531 nm (green) is assigned to the2H11/2→4I15/2. In this work, the strongest peak at 2.0% mol of Er2O3was observed. In this work, suggests that the Er3+ion in gadolinium calcium silicoborate glasses possibly considered as a potential candidate for applications in upconversion-based optical devices. © (2013) Trans Tech Publications, Switzerland.