Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]

Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]

The reaction of bis-(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2], with bis-(diphenyl-phosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis-(1,3-diphenyl-propane-1,3-dionato-2 O,O′)cobalt(II)] - ethyl-enebis(diphenyl-phosphine oxide)-2 O:O′], trans-[Co(C15H11O2)2(C26H24...

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Main Authors: Harding D.J., Harding P., Thurakitseree T., Adams H.
Format: Article
Language:English
Published: 2014
Online Access:http://www.scopus.com/inward/record.url?eid=2-s2.0-34147098501&partnerID=40&md5=8ce6830692c2fe0e387773379168ba5c
http://cmuir.cmu.ac.th/handle/6653943832/5290
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Language: English
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spelling th-cmuir.6653943832-52902014-08-30T02:56:22Z Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2] Harding D.J. Harding P. Thurakitseree T. Adams H. The reaction of bis-(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2], with bis-(diphenyl-phosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis-(1,3-diphenyl-propane-1,3-dionato-2 O,O′)cobalt(II)] - ethyl-enebis(diphenyl-phosphine oxide)-2 O:O′], trans-[Co(C15H11O2)2(C26H24O2P2)] n, as a result of oxidation of the diphos-phine. The Co atom is octa-hedral, with a CoO6 coordination sphere, and the chelating dbm ligands adopt a trans configuration. The Co atom also lies on a centre of inversion, with a further symmetry centre bis-ecting the bridging ethyl-enebis(diphenyl-phosphine oxide) ligand. © International Union of Crystallography 2007. 2014-08-30T02:56:22Z 2014-08-30T02:56:22Z 2007 Article 01082701 10.1107/S010827010700933X ACSCE http://www.scopus.com/inward/record.url?eid=2-s2.0-34147098501&partnerID=40&md5=8ce6830692c2fe0e387773379168ba5c http://cmuir.cmu.ac.th/handle/6653943832/5290 English
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
language English
description The reaction of bis-(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2], with bis-(diphenyl-phosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis-(1,3-diphenyl-propane-1,3-dionato-2 O,O′)cobalt(II)] - ethyl-enebis(diphenyl-phosphine oxide)-2 O:O′], trans-[Co(C15H11O2)2(C26H24O2P2)] n, as a result of oxidation of the diphos-phine. The Co atom is octa-hedral, with a CoO6 coordination sphere, and the chelating dbm ligands adopt a trans configuration. The Co atom also lies on a centre of inversion, with a further symmetry centre bis-ecting the bridging ethyl-enebis(diphenyl-phosphine oxide) ligand. © International Union of Crystallography 2007.
format Article
author Harding D.J.
Harding P.
Thurakitseree T.
Adams H.
spellingShingle Harding D.J.
Harding P.
Thurakitseree T.
Adams H.
Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
author_facet Harding D.J.
Harding P.
Thurakitseree T.
Adams H.
author_sort Harding D.J.
title Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
title_short Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
title_full Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
title_fullStr Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
title_full_unstemmed Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
title_sort unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(ii), [co(dbm)2]
publishDate 2014
url http://www.scopus.com/inward/record.url?eid=2-s2.0-34147098501&partnerID=40&md5=8ce6830692c2fe0e387773379168ba5c
http://cmuir.cmu.ac.th/handle/6653943832/5290
_version_ 1681420397372768256

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