A new 1D coordination polymer of lanthanum-sulfate-1,10-phenanthroline: Synthesis, structure, and photoluminescence property

A 1D coordination framework, {[La2(o-phen)2(SO4)3(H2O)2]}n(1) (o-phen = 1,10-phenanthroline) was hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR, and UV-Vis spectroscopy. The crystal of 1 crystallized in the triclinic P,1. space group, a = 10....

Full description

Saved in:
Bibliographic Details
Main Authors: Bunlawee Yotnoi, Natthaya Meundaeng, Apinpus Rujiwatra
Format: Journal
Published: 2018
Subjects:
Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84902300044&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/53358
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Chiang Mai University
id th-cmuir.6653943832-53358
record_format dspace
spelling th-cmuir.6653943832-533582018-09-04T09:47:43Z A new 1D coordination polymer of lanthanum-sulfate-1,10-phenanthroline: Synthesis, structure, and photoluminescence property Bunlawee Yotnoi Natthaya Meundaeng Apinpus Rujiwatra Chemistry A 1D coordination framework, {[La2(o-phen)2(SO4)3(H2O)2]}n(1) (o-phen = 1,10-phenanthroline) was hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR, and UV-Vis spectroscopy. The crystal of 1 crystallized in the triclinic P,1. space group, a = 10.3228(5) Å, b = 12.3644(7) Å, c = 12.6579(6) Å, α = 72.323(2)°, β = 75.610(2)°, γ = 82.785(2)°, V = 1488.82(13) Å3, Z = 2. The structure exhibits a neutral 1D framework representing a five-connected uninodal 1-periodic net of (3,6)(0,2) topology. The framework structure comprises TPRS-9 {LaO7N2} units, chelating o-phen ligands and bridging sulfates of 3.1110 and 4.2211 coordination modes. These 1D chains are extended into a 3D supramolecular structure by hydrogen bonding interactions of, R22(n) patterns. Thermogravimetric analysis shows the structure to be thermally stable up to approximately 400°C. Photoluminescence investigations on Eu3+and Tb3+doped samples suggest the competition between the ligand-to-metal charge-transfer and energy-transfer processes. Copyright © Taylor & Francis Group, LLC. 2018-09-04T09:47:43Z 2018-09-04T09:47:43Z 2014-01-01 Journal 15533182 15533174 2-s2.0-84902300044 10.1080/15533174.2013.802337 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84902300044&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/53358
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
topic Chemistry
spellingShingle Chemistry
Bunlawee Yotnoi
Natthaya Meundaeng
Apinpus Rujiwatra
A new 1D coordination polymer of lanthanum-sulfate-1,10-phenanthroline: Synthesis, structure, and photoluminescence property
description A 1D coordination framework, {[La2(o-phen)2(SO4)3(H2O)2]}n(1) (o-phen = 1,10-phenanthroline) was hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR, and UV-Vis spectroscopy. The crystal of 1 crystallized in the triclinic P,1. space group, a = 10.3228(5) Å, b = 12.3644(7) Å, c = 12.6579(6) Å, α = 72.323(2)°, β = 75.610(2)°, γ = 82.785(2)°, V = 1488.82(13) Å3, Z = 2. The structure exhibits a neutral 1D framework representing a five-connected uninodal 1-periodic net of (3,6)(0,2) topology. The framework structure comprises TPRS-9 {LaO7N2} units, chelating o-phen ligands and bridging sulfates of 3.1110 and 4.2211 coordination modes. These 1D chains are extended into a 3D supramolecular structure by hydrogen bonding interactions of, R22(n) patterns. Thermogravimetric analysis shows the structure to be thermally stable up to approximately 400°C. Photoluminescence investigations on Eu3+and Tb3+doped samples suggest the competition between the ligand-to-metal charge-transfer and energy-transfer processes. Copyright © Taylor & Francis Group, LLC.
format Journal
author Bunlawee Yotnoi
Natthaya Meundaeng
Apinpus Rujiwatra
author_facet Bunlawee Yotnoi
Natthaya Meundaeng
Apinpus Rujiwatra
author_sort Bunlawee Yotnoi
title A new 1D coordination polymer of lanthanum-sulfate-1,10-phenanthroline: Synthesis, structure, and photoluminescence property
title_short A new 1D coordination polymer of lanthanum-sulfate-1,10-phenanthroline: Synthesis, structure, and photoluminescence property
title_full A new 1D coordination polymer of lanthanum-sulfate-1,10-phenanthroline: Synthesis, structure, and photoluminescence property
title_fullStr A new 1D coordination polymer of lanthanum-sulfate-1,10-phenanthroline: Synthesis, structure, and photoluminescence property
title_full_unstemmed A new 1D coordination polymer of lanthanum-sulfate-1,10-phenanthroline: Synthesis, structure, and photoluminescence property
title_sort new 1d coordination polymer of lanthanum-sulfate-1,10-phenanthroline: synthesis, structure, and photoluminescence property
publishDate 2018
url https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84902300044&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/53358
_version_ 1681424120341856256