Size-controlled preparation of gold nanoclusters stabilized by high-viscosity hydrophilic polymers using a microflow reactor

Gold nanoclusters stabilized by high-viscosity hydrophilic polymers such as poly(N-vinyl-2-pyrrolidone) (K-90) (Au:PVP K-90) and star-shaped polymers (Au:star poly(MOVE)200) were prepared in a continuous flowing process using a microflow reactor. Two types of metal/stainless steel-free microflow rea...

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Main Authors: Setsiri Haesuwannakij, Weeranuch Karuehanon, Vijay Laksami Mishra, Hiroaki Kitahara, Hidehiro Sakurai, Shokyoku Kanaoka, Sadahito Aoshima
格式: 雜誌
出版: 2018
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在線閱讀:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84895905037&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/53363
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總結:Gold nanoclusters stabilized by high-viscosity hydrophilic polymers such as poly(N-vinyl-2-pyrrolidone) (K-90) (Au:PVP K-90) and star-shaped polymers (Au:star poly(MOVE)200) were prepared in a continuous flowing process using a microflow reactor. Two types of metal/stainless steel-free microflow reactors (techno-applications COMET X-1 and Sigma-Aldrich type S02) were selected to avoid contamination with other metals. The resultant Au:PVP(K-90) and Au:star poly(MOVE)200clusters were significantly smaller with a narrower size distribution than those prepared by the batch process. Graphical Abstract: [Figure not available: see fulltext.]. © 2013 Springer-Verlag Wien.