Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system

Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system

The phase transition behavior of the (1-x) PbZrO3-xPb(Co 1/3Nb2/3)O3 (PZCN) solid solution system (0 ≤ x ≤ 0.30) has been investigated by X-ray diffraction and DSC. In the solid solution, for x ≤ 0.20, the transition shows a first-order phase transition behavior and its antiferroelectric (AFE) cryst...

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Main Authors: Banlue W., Muanghlua R., Vittayakorn W.C., Vittayakom N.
Format: Conference or Workshop Item
Language:English
Published: 2014
Online Access:http://www.scopus.com/inward/record.url?eid=2-s2.0-62949103017&partnerID=40&md5=f4064fc16c3965a6f8aaa531b2b0ee10
http://cmuir.cmu.ac.th/handle/6653943832/5397
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Institution: Chiang Mai University
Language: English
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spelling th-cmuir.6653943832-53972014-08-30T02:56:29Z Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system Banlue W. Muanghlua R. Vittayakorn W.C. Vittayakom N. The phase transition behavior of the (1-x) PbZrO3-xPb(Co 1/3Nb2/3)O3 (PZCN) solid solution system (0 ≤ x ≤ 0.30) has been investigated by X-ray diffraction and DSC. In the solid solution, for x ≤ 0.20, the transition shows a first-order phase transition behavior and its antiferroelectric (AFE) crystal structure is orthorhombic. The transition temperature gradually decreases with increased Co2+/Nb5+ concentration. On the composition range 0.20 ≤x≤ 0.30, a typical relaxor-like behavior is displayed. The low temperature crystal structure is pseudo-cubic in this composition range. With these data, the ferroelectric phase diagram between PZ and PCoN has been established. © 2008 Trans Tech Publications, Switzerland. 2014-08-30T02:56:29Z 2014-08-30T02:56:29Z 2008 Conference Paper 9780878493562 10226680 75596 http://www.scopus.com/inward/record.url?eid=2-s2.0-62949103017&partnerID=40&md5=f4064fc16c3965a6f8aaa531b2b0ee10 http://cmuir.cmu.ac.th/handle/6653943832/5397 English
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
language English
description The phase transition behavior of the (1-x) PbZrO3-xPb(Co 1/3Nb2/3)O3 (PZCN) solid solution system (0 ≤ x ≤ 0.30) has been investigated by X-ray diffraction and DSC. In the solid solution, for x ≤ 0.20, the transition shows a first-order phase transition behavior and its antiferroelectric (AFE) crystal structure is orthorhombic. The transition temperature gradually decreases with increased Co2+/Nb5+ concentration. On the composition range 0.20 ≤x≤ 0.30, a typical relaxor-like behavior is displayed. The low temperature crystal structure is pseudo-cubic in this composition range. With these data, the ferroelectric phase diagram between PZ and PCoN has been established. © 2008 Trans Tech Publications, Switzerland.
format Conference or Workshop Item
author Banlue W.
Muanghlua R.
Vittayakorn W.C.
Vittayakom N.
spellingShingle Banlue W.
Muanghlua R.
Vittayakorn W.C.
Vittayakom N.
Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
author_facet Banlue W.
Muanghlua R.
Vittayakorn W.C.
Vittayakom N.
author_sort Banlue W.
title Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
title_short Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
title_full Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
title_fullStr Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
title_full_unstemmed Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
title_sort synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)pbzro3-xpb(co1/3nb 2/3)o3 solid solution system
publishDate 2014
url http://www.scopus.com/inward/record.url?eid=2-s2.0-62949103017&partnerID=40&md5=f4064fc16c3965a6f8aaa531b2b0ee10
http://cmuir.cmu.ac.th/handle/6653943832/5397
_version_ 1681420417817903104

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