Co-Ti-O complex oxides: Hydrothermal synthesis, phase characterization, color analysis and catalytic activity assessment

© 2015, Chiang Mai University. All rights reserved. The hydrothermal synthesis of Co-Ti-O complex oxide nanoparticles from the reaction between TiO2and Co(NO3)2.6H2O using the stoichiometric ratio to yield Co2TiO4and NaOH as mineralizer have been investigated. The particles were characterized by pow...

Full description

Saved in:
Bibliographic Details
Main Authors: Apinpus Rujiwatra, Natthawat Semakul, Sireenart Surinwong, Metta Chareonpanich
Format: Journal
Published: 2018
Subjects:
Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84946575859&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/54184
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Chiang Mai University
id th-cmuir.6653943832-54184
record_format dspace
spelling th-cmuir.6653943832-541842018-09-04T10:26:24Z Co-Ti-O complex oxides: Hydrothermal synthesis, phase characterization, color analysis and catalytic activity assessment Apinpus Rujiwatra Natthawat Semakul Sireenart Surinwong Metta Chareonpanich Biochemistry, Genetics and Molecular Biology Chemistry Materials Science Mathematics Physics and Astronomy © 2015, Chiang Mai University. All rights reserved. The hydrothermal synthesis of Co-Ti-O complex oxide nanoparticles from the reaction between TiO2and Co(NO3)2.6H2O using the stoichiometric ratio to yield Co2TiO4and NaOH as mineralizer have been investigated. The particles were characterized by powder X-ray diffraction, selected area electron diffraction, scanning electron and transmission electron microscopies, UV-Vis, infrared and Raman spectroscopies, X-ray absorption near-edge spectroscopy, thermogravimetric analysis and gas sorption measurements. Evidences on the pathogenic formation of Co3O4and CoTiO3are illustrated, and the unlikely in yielding a single phase of Co2TiO4is revealed. Detailed phase characterization is discussed. The particles showed a dark bluish green color, two different morphologies of rhombus and needle shape with a mean particle size of 150 nm, a remarkably narrow pore size distribution below 75 Å, and type II gas sorption behavior. An excellent performance as a catalyst toward the Fischer-Tropsch synthesis with 35% of CO conversion and a high selectivity toward the C10, has been revealed. 2018-09-04T10:09:11Z 2018-09-04T10:09:11Z 2015-01-01 Journal 01252526 2-s2.0-84946575859 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84946575859&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/54184
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
topic Biochemistry, Genetics and Molecular Biology
Chemistry
Materials Science
Mathematics
Physics and Astronomy
spellingShingle Biochemistry, Genetics and Molecular Biology
Chemistry
Materials Science
Mathematics
Physics and Astronomy
Apinpus Rujiwatra
Natthawat Semakul
Sireenart Surinwong
Metta Chareonpanich
Co-Ti-O complex oxides: Hydrothermal synthesis, phase characterization, color analysis and catalytic activity assessment
description © 2015, Chiang Mai University. All rights reserved. The hydrothermal synthesis of Co-Ti-O complex oxide nanoparticles from the reaction between TiO2and Co(NO3)2.6H2O using the stoichiometric ratio to yield Co2TiO4and NaOH as mineralizer have been investigated. The particles were characterized by powder X-ray diffraction, selected area electron diffraction, scanning electron and transmission electron microscopies, UV-Vis, infrared and Raman spectroscopies, X-ray absorption near-edge spectroscopy, thermogravimetric analysis and gas sorption measurements. Evidences on the pathogenic formation of Co3O4and CoTiO3are illustrated, and the unlikely in yielding a single phase of Co2TiO4is revealed. Detailed phase characterization is discussed. The particles showed a dark bluish green color, two different morphologies of rhombus and needle shape with a mean particle size of 150 nm, a remarkably narrow pore size distribution below 75 Å, and type II gas sorption behavior. An excellent performance as a catalyst toward the Fischer-Tropsch synthesis with 35% of CO conversion and a high selectivity toward the C10, has been revealed.
format Journal
author Apinpus Rujiwatra
Natthawat Semakul
Sireenart Surinwong
Metta Chareonpanich
author_facet Apinpus Rujiwatra
Natthawat Semakul
Sireenart Surinwong
Metta Chareonpanich
author_sort Apinpus Rujiwatra
title Co-Ti-O complex oxides: Hydrothermal synthesis, phase characterization, color analysis and catalytic activity assessment
title_short Co-Ti-O complex oxides: Hydrothermal synthesis, phase characterization, color analysis and catalytic activity assessment
title_full Co-Ti-O complex oxides: Hydrothermal synthesis, phase characterization, color analysis and catalytic activity assessment
title_fullStr Co-Ti-O complex oxides: Hydrothermal synthesis, phase characterization, color analysis and catalytic activity assessment
title_full_unstemmed Co-Ti-O complex oxides: Hydrothermal synthesis, phase characterization, color analysis and catalytic activity assessment
title_sort co-ti-o complex oxides: hydrothermal synthesis, phase characterization, color analysis and catalytic activity assessment
publishDate 2018
url https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84946575859&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/54184
_version_ 1681424273950900224