Ph<inf>3</inf>P-I<inf>2</inf>mediated aryl esterification with a mechanistic insight
© 2016 Elsevier Ltd. All rights reserved. In order to better understand the reaction mechanism and to obtain optimal conditions, the Ph3P-I2/Et3N mediated aryl esterification reaction was thoroughly investigated. Using a specific reagent addition sequence, the reaction proceeds remarkably well espec...
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th-cmuir.6653943832-552082018-09-05T03:12:16Z Ph<inf>3</inf>P-I<inf>2</inf>mediated aryl esterification with a mechanistic insight Wong Phakhodee Chuthamat Duangkamol Mookda Pattarawarapan Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics © 2016 Elsevier Ltd. All rights reserved. In order to better understand the reaction mechanism and to obtain optimal conditions, the Ph3P-I2/Et3N mediated aryl esterification reaction was thoroughly investigated. Using a specific reagent addition sequence, the reaction proceeds remarkably well especially with acidic substrates.31P NMR studies revealed that the formation of an aryloxyphosphonium salt is crucial in governing the reaction path toward the formation of phenolic esters. 2018-09-05T02:53:05Z 2018-09-05T02:53:05Z 2016-05-11 Journal 18733581 00404039 2-s2.0-84979486626 10.1016/j.tetlet.2016.03.105 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84979486626&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/55208 |
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Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics |
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Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics Wong Phakhodee Chuthamat Duangkamol Mookda Pattarawarapan Ph<inf>3</inf>P-I<inf>2</inf>mediated aryl esterification with a mechanistic insight |
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© 2016 Elsevier Ltd. All rights reserved. In order to better understand the reaction mechanism and to obtain optimal conditions, the Ph3P-I2/Et3N mediated aryl esterification reaction was thoroughly investigated. Using a specific reagent addition sequence, the reaction proceeds remarkably well especially with acidic substrates.31P NMR studies revealed that the formation of an aryloxyphosphonium salt is crucial in governing the reaction path toward the formation of phenolic esters. |
| format |
Journal |
| author |
Wong Phakhodee Chuthamat Duangkamol Mookda Pattarawarapan |
| author_facet |
Wong Phakhodee Chuthamat Duangkamol Mookda Pattarawarapan |
| author_sort |
Wong Phakhodee |
| title |
Ph<inf>3</inf>P-I<inf>2</inf>mediated aryl esterification with a mechanistic insight |
| title_short |
Ph<inf>3</inf>P-I<inf>2</inf>mediated aryl esterification with a mechanistic insight |
| title_full |
Ph<inf>3</inf>P-I<inf>2</inf>mediated aryl esterification with a mechanistic insight |
| title_fullStr |
Ph<inf>3</inf>P-I<inf>2</inf>mediated aryl esterification with a mechanistic insight |
| title_full_unstemmed |
Ph<inf>3</inf>P-I<inf>2</inf>mediated aryl esterification with a mechanistic insight |
| title_sort |
ph<inf>3</inf>p-i<inf>2</inf>mediated aryl esterification with a mechanistic insight |
| publishDate |
2018 |
| url |
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84979486626&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/55208 |
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