Photovoltaic performances of Cu<inf>2-x</inf>Te sensitizer based on undoped and indium³⁺-doped TiO<inf>2</inf>photoelectrodes and assembled counter electrodes

• Main Authors: Pornpimol Srathongluan, Rattanakorn Kuhamaneechot, Prapatsawan Sukthao, Veeramol Vailikhit, Supab Choopun, Auttasit Tubtimtae
• Format: Journal
• Published: 2018
• Subjects: Chemical Engineering; Materials Science
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84945587274&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/55387
• Institution: Chiang Mai University

© 2015 Elsevier Inc. Novel binary Cu2-xTe nanoparticles based on undoped and indium-doped TiO2photoelectrodes were synthesized using a successive ionic layer adsorption and reaction (SILAR) technique as a sensitizer for liquid-junction solar cells. A larger diameter of TiO2promoted a narrower energy band gap after indium doping, attributing to yield a broader absorption range of nanoparticle sensitizer due to the increasing amount of Cu2-xTe NPs on TiO2surface. The atomic percentages showed the stoichiometric formation of Cu2Te incorporated in a Cu2-xTe structure. The best photovoltaic performance with the lower SILAR cycle, i.e., n=13 was performed after indium doping in both of carbon and Cu2S CEs and revealed that the efficiency of 0.73% under the radiant 100 mW/cm2(AM 1.5G). The electrochemical impedance spectroscopy (EIS) was used to investigate the electrical properties via effect of material doping and counter electrodes with a lower charge-transfer resistance (Rct) and it was also found that the electron lifetime was improved after the sample doped with indium and assembled with carbon CE.