The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives

The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives

© 2016 The Royal Society of Chemistry. A series of 1,1′-bis(sulfonyl)ferrocene compounds were produced via the 1,1′-bis(sulfonate)ferrocene ammonium salt. This compound can be readily converted to 1,1′ bis(sulfonylchloride)ferrocene. By varying stoichiometry and reaction times, both mono- and bis-su...

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Main Authors: Kullapa Chanawanno, Cole Holstrom, Laura A. Crandall, Henry Dodge, Victor N. Nemykin, Richard S. Herrick, Christopher J. Ziegler
Format: Journal
Published: 2018
Subjects:
Chemistry
Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84987778387&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/55482
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Institution: Chiang Mai University
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spelling th-cmuir.6653943832-554822018-09-05T02:56:56Z The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives Kullapa Chanawanno Cole Holstrom Laura A. Crandall Henry Dodge Victor N. Nemykin Richard S. Herrick Christopher J. Ziegler Chemistry © 2016 The Royal Society of Chemistry. A series of 1,1′-bis(sulfonyl)ferrocene compounds were produced via the 1,1′-bis(sulfonate)ferrocene ammonium salt. This compound can be readily converted to 1,1′ bis(sulfonylchloride)ferrocene. By varying stoichiometry and reaction times, both mono- and bis-sulfonamide derivatives can be synthesized. All new compounds presented in this report have been structurally characterized. The structures of the bis-sulfonamide systems are similar to the well-studied bis(amide) ferrocene compounds. Intermolecular hydrogen bonding is observed, typically between NH and SO groups of neighboring sulfonamides. However in the bis(GABA) derivative, intermolecular NH to CO hydrogen bonding interactions are present. 2018-09-05T02:56:56Z 2018-09-05T02:56:56Z 2016-01-01 Journal 14779234 14779226 2-s2.0-84987778387 10.1039/c6dt02669a https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84987778387&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/55482
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
topic Chemistry
spellingShingle Chemistry
Kullapa Chanawanno
Cole Holstrom
Laura A. Crandall
Henry Dodge
Victor N. Nemykin
Richard S. Herrick
Christopher J. Ziegler
The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives
description © 2016 The Royal Society of Chemistry. A series of 1,1′-bis(sulfonyl)ferrocene compounds were produced via the 1,1′-bis(sulfonate)ferrocene ammonium salt. This compound can be readily converted to 1,1′ bis(sulfonylchloride)ferrocene. By varying stoichiometry and reaction times, both mono- and bis-sulfonamide derivatives can be synthesized. All new compounds presented in this report have been structurally characterized. The structures of the bis-sulfonamide systems are similar to the well-studied bis(amide) ferrocene compounds. Intermolecular hydrogen bonding is observed, typically between NH and SO groups of neighboring sulfonamides. However in the bis(GABA) derivative, intermolecular NH to CO hydrogen bonding interactions are present.
format Journal
author Kullapa Chanawanno
Cole Holstrom
Laura A. Crandall
Henry Dodge
Victor N. Nemykin
Richard S. Herrick
Christopher J. Ziegler
author_facet Kullapa Chanawanno
Cole Holstrom
Laura A. Crandall
Henry Dodge
Victor N. Nemykin
Richard S. Herrick
Christopher J. Ziegler
author_sort Kullapa Chanawanno
title The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives
title_short The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives
title_full The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives
title_fullStr The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives
title_full_unstemmed The synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives
title_sort synthesis and structures of 1,1′-bis(sulfonyl)ferrocene derivatives
publishDate 2018
url https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84987778387&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/55482
_version_ 1681424513957363712

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