Doped soap membranes selectively permeate a chiral isomer
Soap films can not only be made with sub-μm thickness, they can have intrinsic permeabilities comparable to many commercial membranes, permitting very high transmembrane flux. Soap films readily incorporate a wide range of modifiers to allow highly tailored selectivity: We show that incorporating α-...
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th-cmuir.6653943832-56412014-08-30T03:23:15Z Doped soap membranes selectively permeate a chiral isomer Kanyanee T. Jakmunee J. Grudpan K. Dasgupta P.K. Soap films can not only be made with sub-μm thickness, they can have intrinsic permeabilities comparable to many commercial membranes, permitting very high transmembrane flux. Soap films readily incorporate a wide range of modifiers to allow highly tailored selectivity: We show that incorporating α-cyclodextrin in an 890 nm thick Triton-X-100 film allows, in a single stage, a high degree of chirally selective transport (1.6:1) of α(+)-pinene over α(-)-pinene. © 2010 American Chemical Society. 2014-08-30T03:23:15Z 2014-08-30T03:23:15Z 2010 Article 27863 10.1021/ja109461r JACSA http://www.scopus.com/inward/record.url?eid=2-s2.0-78650616297&partnerID=40&md5=9930d41a289f00520a835f187413c132 http://www.ncbi.nlm.nih.gov/pubmed/21138262 http://cmuir.cmu.ac.th/handle/6653943832/5641 English |
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Soap films can not only be made with sub-μm thickness, they can have intrinsic permeabilities comparable to many commercial membranes, permitting very high transmembrane flux. Soap films readily incorporate a wide range of modifiers to allow highly tailored selectivity: We show that incorporating α-cyclodextrin in an 890 nm thick Triton-X-100 film allows, in a single stage, a high degree of chirally selective transport (1.6:1) of α(+)-pinene over α(-)-pinene. © 2010 American Chemical Society. |
format |
Article |
author |
Kanyanee T. Jakmunee J. Grudpan K. Dasgupta P.K. |
spellingShingle |
Kanyanee T. Jakmunee J. Grudpan K. Dasgupta P.K. Doped soap membranes selectively permeate a chiral isomer |
author_facet |
Kanyanee T. Jakmunee J. Grudpan K. Dasgupta P.K. |
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Kanyanee T. |
title |
Doped soap membranes selectively permeate a chiral isomer |
title_short |
Doped soap membranes selectively permeate a chiral isomer |
title_full |
Doped soap membranes selectively permeate a chiral isomer |
title_fullStr |
Doped soap membranes selectively permeate a chiral isomer |
title_full_unstemmed |
Doped soap membranes selectively permeate a chiral isomer |
title_sort |
doped soap membranes selectively permeate a chiral isomer |
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2014 |
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http://www.scopus.com/inward/record.url?eid=2-s2.0-78650616297&partnerID=40&md5=9930d41a289f00520a835f187413c132 http://www.ncbi.nlm.nih.gov/pubmed/21138262 http://cmuir.cmu.ac.th/handle/6653943832/5641 |
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