Ethylene insertion in the presence of new alkoxysilane electron donors for Ziegler-Natta catalyzed polyethylene

• Main Authors: Sutiam Kruawan, Manussada Ratanasak, Rungroj Chanajaree, Thanyada Rungrotmongkol, Oraphan Saengsawang, Vudhichai Parasuk, Nawee Kungwan, Supot Hannongbua
• Format: Journal
• Published: 2018
• Subjects: Biochemistry, Genetics and Molecular Biology; Chemistry; Physics and Astronomy
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85018624812&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/56731
• Institution: Chiang Mai University

© 2017 Density functional theory (DFT) calculations have been carried out to investigate the ethylene insertion pathway using a Ziegler-Natta catalyst in the absence and presence of electron donor (ED) systems on the (1 1 0) MgCl2surface. The coadsorptions of four different EDs i.e. Si(OEt)mCln(m + ...