Lanthanide Coordination Polymers of Mixed Phthalate/Adipate for Ratiometric Temperature Sensing in the Upper-Intermediate Temperature Range

Lanthanide Coordination Polymers of Mixed Phthalate/Adipate for Ratiometric Temperature Sensing in the Upper-Intermediate Temperature Range

© 2018 American Chemical Society. Based on the mixed phthalate (phth2-) and adipate (ad2-), [Nd2(ad)(phth)2(H2O)4] (I) and [Ln(ad)0.5(phth)(H2O)2] (Ln = EuIII(II), GdIII(III), TbIII(IV), DyIII(V), ErIII(VI), TmIII(VII), 1EuIII:10TbIII(VIII), 3EuIII:10TbIII(IX), and 5EuIII:10TbIII(X)) were synthesize...

Full description

Saved in:
Bibliographic Details
Main Authors: Thammanoon Chuasaard, Athipong Ngamjarurojana, Sireenart Surinwong, Takumi Konno, Sareeya Bureekaew, Apinpus Rujiwatra
Format: Journal
Published: 2018
Subjects:
Chemistry
Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85043245203&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/58458
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Chiang Mai University
id th-cmuir.6653943832-58458
record_format dspace
spelling th-cmuir.6653943832-584582018-09-05T04:24:38Z Lanthanide Coordination Polymers of Mixed Phthalate/Adipate for Ratiometric Temperature Sensing in the Upper-Intermediate Temperature Range Thammanoon Chuasaard Athipong Ngamjarurojana Sireenart Surinwong Takumi Konno Sareeya Bureekaew Apinpus Rujiwatra Chemistry © 2018 American Chemical Society. Based on the mixed phthalate (phth2-) and adipate (ad2-), [Nd2(ad)(phth)2(H2O)4] (I) and [Ln(ad)0.5(phth)(H2O)2] (Ln = EuIII(II), GdIII(III), TbIII(IV), DyIII(V), ErIII(VI), TmIII(VII), 1EuIII:10TbIII(VIII), 3EuIII:10TbIII(IX), and 5EuIII:10TbIII(X)) were synthesized and characterized. Complexes VIII-X show excellent ratiometric temperature sensing behavior in physiological and higher temperature ranges (303-423 K) rendered by the TbIII-to-EuIIIenergy transfer process. The efficiency of the process as illustrated through the lifetime measurements depends on both the EuIII:TbIIImole ratio and the temperature. The performance of X in terms of relative sensitivity (Sr), temperature resolution, and measurement repeatability were determined, revealing the maximum Sr(Sm) of 1.21%·K-1at 303 K with reliable temperature resolution and excellent repeatability. 2018-09-05T04:24:38Z 2018-09-05T04:24:38Z 2018-03-05 Journal 1520510X 00201669 2-s2.0-85043245203 10.1021/acs.inorgchem.7b03016 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85043245203&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/58458
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
topic Chemistry
spellingShingle Chemistry
Thammanoon Chuasaard
Athipong Ngamjarurojana
Sireenart Surinwong
Takumi Konno
Sareeya Bureekaew
Apinpus Rujiwatra
Lanthanide Coordination Polymers of Mixed Phthalate/Adipate for Ratiometric Temperature Sensing in the Upper-Intermediate Temperature Range
description © 2018 American Chemical Society. Based on the mixed phthalate (phth2-) and adipate (ad2-), [Nd2(ad)(phth)2(H2O)4] (I) and [Ln(ad)0.5(phth)(H2O)2] (Ln = EuIII(II), GdIII(III), TbIII(IV), DyIII(V), ErIII(VI), TmIII(VII), 1EuIII:10TbIII(VIII), 3EuIII:10TbIII(IX), and 5EuIII:10TbIII(X)) were synthesized and characterized. Complexes VIII-X show excellent ratiometric temperature sensing behavior in physiological and higher temperature ranges (303-423 K) rendered by the TbIII-to-EuIIIenergy transfer process. The efficiency of the process as illustrated through the lifetime measurements depends on both the EuIII:TbIIImole ratio and the temperature. The performance of X in terms of relative sensitivity (Sr), temperature resolution, and measurement repeatability were determined, revealing the maximum Sr(Sm) of 1.21%·K-1at 303 K with reliable temperature resolution and excellent repeatability.
format Journal
author Thammanoon Chuasaard
Athipong Ngamjarurojana
Sireenart Surinwong
Takumi Konno
Sareeya Bureekaew
Apinpus Rujiwatra
author_facet Thammanoon Chuasaard
Athipong Ngamjarurojana
Sireenart Surinwong
Takumi Konno
Sareeya Bureekaew
Apinpus Rujiwatra
author_sort Thammanoon Chuasaard
title Lanthanide Coordination Polymers of Mixed Phthalate/Adipate for Ratiometric Temperature Sensing in the Upper-Intermediate Temperature Range
title_short Lanthanide Coordination Polymers of Mixed Phthalate/Adipate for Ratiometric Temperature Sensing in the Upper-Intermediate Temperature Range
title_full Lanthanide Coordination Polymers of Mixed Phthalate/Adipate for Ratiometric Temperature Sensing in the Upper-Intermediate Temperature Range
title_fullStr Lanthanide Coordination Polymers of Mixed Phthalate/Adipate for Ratiometric Temperature Sensing in the Upper-Intermediate Temperature Range
title_full_unstemmed Lanthanide Coordination Polymers of Mixed Phthalate/Adipate for Ratiometric Temperature Sensing in the Upper-Intermediate Temperature Range
title_sort lanthanide coordination polymers of mixed phthalate/adipate for ratiometric temperature sensing in the upper-intermediate temperature range
publishDate 2018
url https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85043245203&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/58458
_version_ 1681425069093421056

Similar Items