Intercalated brucite-type layered cobalt(II) hydroxysulfate
In an attempt to synthesize new cobalt(II) sulfate framework structures using 1,4-diazabicyclo[2.2.2]octane as a template, crystals of poly[0.35-[hexaaquacobalt(II)] [tri-μ-hydroxido-μ-sulfato-dicobalt(II)]], {[Co(H2O)6]0.35[Co2(OH) 3(SO4)]}n, were obtained as a mixture with [Co(H2O)6]SO4 crystals....
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2014
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th-cmuir.6653943832-58462014-08-30T03:23:32Z Intercalated brucite-type layered cobalt(II) hydroxysulfate Yotnoi B. Luachan S. Prior T.J. Rujiwatra A. In an attempt to synthesize new cobalt(II) sulfate framework structures using 1,4-diazabicyclo[2.2.2]octane as a template, crystals of poly[0.35-[hexaaquacobalt(II)] [tri-μ-hydroxido-μ-sulfato-dicobalt(II)]], {[Co(H2O)6]0.35[Co2(OH) 3(SO4)]}n, were obtained as a mixture with [Co(H2O)6]SO4 crystals. The crystal structure can be described as being constructed from discrete brucite-type [Co 4(OH)6(SO4)2] layers, each of which is built up from edge-shared [Co(OH)6] and [Co(OH) 4-(OSO3)2] octahedra, with partial intercalation by [Co(H2O)6]2+ ions. The absence of ca 30% of the [Co(H2O)6]2+ cations indicates partial oxidation of cobalt(II) to cobalt(III) within the layer. 2014-08-30T03:23:32Z 2014-08-30T03:23:32Z 2009 Article 16005368 10.1107/S160053680902251X http://www.scopus.com/inward/record.url?eid=2-s2.0-67650832072&partnerID=40&md5=c5decfbac9e7a34bc4db702a457d2581 http://cmuir.cmu.ac.th/handle/6653943832/5846 English |
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English |
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In an attempt to synthesize new cobalt(II) sulfate framework structures using 1,4-diazabicyclo[2.2.2]octane as a template, crystals of poly[0.35-[hexaaquacobalt(II)] [tri-μ-hydroxido-μ-sulfato-dicobalt(II)]], {[Co(H2O)6]0.35[Co2(OH) 3(SO4)]}n, were obtained as a mixture with [Co(H2O)6]SO4 crystals. The crystal structure can be described as being constructed from discrete brucite-type [Co 4(OH)6(SO4)2] layers, each of which is built up from edge-shared [Co(OH)6] and [Co(OH) 4-(OSO3)2] octahedra, with partial intercalation by [Co(H2O)6]2+ ions. The absence of ca 30% of the [Co(H2O)6]2+ cations indicates partial oxidation of cobalt(II) to cobalt(III) within the layer. |
| format |
Article |
| author |
Yotnoi B. Luachan S. Prior T.J. Rujiwatra A. |
| spellingShingle |
Yotnoi B. Luachan S. Prior T.J. Rujiwatra A. Intercalated brucite-type layered cobalt(II) hydroxysulfate |
| author_facet |
Yotnoi B. Luachan S. Prior T.J. Rujiwatra A. |
| author_sort |
Yotnoi B. |
| title |
Intercalated brucite-type layered cobalt(II) hydroxysulfate |
| title_short |
Intercalated brucite-type layered cobalt(II) hydroxysulfate |
| title_full |
Intercalated brucite-type layered cobalt(II) hydroxysulfate |
| title_fullStr |
Intercalated brucite-type layered cobalt(II) hydroxysulfate |
| title_full_unstemmed |
Intercalated brucite-type layered cobalt(II) hydroxysulfate |
| title_sort |
intercalated brucite-type layered cobalt(ii) hydroxysulfate |
| publishDate |
2014 |
| url |
http://www.scopus.com/inward/record.url?eid=2-s2.0-67650832072&partnerID=40&md5=c5decfbac9e7a34bc4db702a457d2581 http://cmuir.cmu.ac.th/handle/6653943832/5846 |
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1681420502645604352 |