Phase separation and crystallization in LiNbO3/SiO2 glasses
Various samples with the compositions (100 - x)LiNbO3·xSiO2 (with x = 10, 20, 25, 30, 35, 40, 50 and 60) were prepared by conventional melting technique. Samples with 20 ≤ x ≤ 35 were transparent, while products with x = 10 or x ≥40 were at least partly opaque under the conditions supplied. TEM-micr...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
2014
|
| Online Access: | http://www.scopus.com/inward/record.url?eid=2-s2.0-58149172035&partnerID=40&md5=a076c45097da02e2ac8bb0570459e728 http://cmuir.cmu.ac.th/handle/6653943832/5934 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Chiang Mai University |
| Language: | English |
| id |
th-cmuir.6653943832-5934 |
|---|---|
| record_format |
dspace |
| spelling |
th-cmuir.6653943832-59342014-08-30T03:23:38Z Phase separation and crystallization in LiNbO3/SiO2 glasses Prapitpongwanich P. Pengpat K. Russel C. Various samples with the compositions (100 - x)LiNbO3·xSiO2 (with x = 10, 20, 25, 30, 35, 40, 50 and 60) were prepared by conventional melting technique. Samples with 20 ≤ x ≤ 35 were transparent, while products with x = 10 or x ≥40 were at least partly opaque under the conditions supplied. TEM-micrographs of replicas gave evidence on phase separation in these glasses. At SiO2-concentrations >30 mol%, the formed structures consist of SiO2-rich droplets in a LiNbO3-rich matrix phase. The size of the structures increases with increasing SiO2-concentration. At an SiO2-concentration of 50 mol%, the droplets are as large as 450 nm. During thermal treatment, the LiNbO3-rich matrix phase crystallizes and forms lithium niobate. © 2008 Elsevier B.V. All rights reserved. 2014-08-30T03:23:38Z 2014-08-30T03:23:38Z 2009 Article 02540584 10.1016/j.matchemphys.2008.08.070 MCHPD http://www.scopus.com/inward/record.url?eid=2-s2.0-58149172035&partnerID=40&md5=a076c45097da02e2ac8bb0570459e728 http://cmuir.cmu.ac.th/handle/6653943832/5934 English |
| institution |
Chiang Mai University |
| building |
Chiang Mai University Library |
| country |
Thailand |
| collection |
CMU Intellectual Repository |
| language |
English |
| description |
Various samples with the compositions (100 - x)LiNbO3·xSiO2 (with x = 10, 20, 25, 30, 35, 40, 50 and 60) were prepared by conventional melting technique. Samples with 20 ≤ x ≤ 35 were transparent, while products with x = 10 or x ≥40 were at least partly opaque under the conditions supplied. TEM-micrographs of replicas gave evidence on phase separation in these glasses. At SiO2-concentrations >30 mol%, the formed structures consist of SiO2-rich droplets in a LiNbO3-rich matrix phase. The size of the structures increases with increasing SiO2-concentration. At an SiO2-concentration of 50 mol%, the droplets are as large as 450 nm. During thermal treatment, the LiNbO3-rich matrix phase crystallizes and forms lithium niobate. © 2008 Elsevier B.V. All rights reserved. |
| format |
Article |
| author |
Prapitpongwanich P. Pengpat K. Russel C. |
| spellingShingle |
Prapitpongwanich P. Pengpat K. Russel C. Phase separation and crystallization in LiNbO3/SiO2 glasses |
| author_facet |
Prapitpongwanich P. Pengpat K. Russel C. |
| author_sort |
Prapitpongwanich P. |
| title |
Phase separation and crystallization in LiNbO3/SiO2 glasses |
| title_short |
Phase separation and crystallization in LiNbO3/SiO2 glasses |
| title_full |
Phase separation and crystallization in LiNbO3/SiO2 glasses |
| title_fullStr |
Phase separation and crystallization in LiNbO3/SiO2 glasses |
| title_full_unstemmed |
Phase separation and crystallization in LiNbO3/SiO2 glasses |
| title_sort |
phase separation and crystallization in linbo3/sio2 glasses |
| publishDate |
2014 |
| url |
http://www.scopus.com/inward/record.url?eid=2-s2.0-58149172035&partnerID=40&md5=a076c45097da02e2ac8bb0570459e728 http://cmuir.cmu.ac.th/handle/6653943832/5934 |
| _version_ |
1681420519099858944 |