Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system

Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system

The phase transition behavior of the (1-x) PbZrO3-xPb(Co 1/3Nb2/3)O3 (PZCN) solid solution system (0 ≤ x ≤ 0.30) has been investigated by X-ray diffraction and DSC. In the solid solution, for x ≤ 0.20, the transition shows a first-order phase transition behavior and its antiferroelectric (AFE) cryst...

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Main Authors: W. Banlue, R. Muanghlua, W. C. Vittayakorn, N. Vittayakom
Format: Book Series
Published: 2018
Subjects:
Engineering
Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=62949103017&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/60397
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Institution: Chiang Mai University
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spelling th-cmuir.6653943832-603972018-09-10T03:41:54Z Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system W. Banlue R. Muanghlua W. C. Vittayakorn N. Vittayakom Engineering The phase transition behavior of the (1-x) PbZrO3-xPb(Co 1/3Nb2/3)O3 (PZCN) solid solution system (0 ≤ x ≤ 0.30) has been investigated by X-ray diffraction and DSC. In the solid solution, for x ≤ 0.20, the transition shows a first-order phase transition behavior and its antiferroelectric (AFE) crystal structure is orthorhombic. The transition temperature gradually decreases with increased Co2+/Nb5+ concentration. On the composition range 0.20 ≤x≤ 0.30, a typical relaxor-like behavior is displayed. The low temperature crystal structure is pseudo-cubic in this composition range. With these data, the ferroelectric phase diagram between PZ and PCoN has been established. © 2008 Trans Tech Publications, Switzerland. 2018-09-10T03:41:54Z 2018-09-10T03:41:54Z 2008-12-01 Book Series 10226680 2-s2.0-62949103017 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=62949103017&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/60397
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
topic Engineering
spellingShingle Engineering
W. Banlue
R. Muanghlua
W. C. Vittayakorn
N. Vittayakom
Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
description The phase transition behavior of the (1-x) PbZrO3-xPb(Co 1/3Nb2/3)O3 (PZCN) solid solution system (0 ≤ x ≤ 0.30) has been investigated by X-ray diffraction and DSC. In the solid solution, for x ≤ 0.20, the transition shows a first-order phase transition behavior and its antiferroelectric (AFE) crystal structure is orthorhombic. The transition temperature gradually decreases with increased Co2+/Nb5+ concentration. On the composition range 0.20 ≤x≤ 0.30, a typical relaxor-like behavior is displayed. The low temperature crystal structure is pseudo-cubic in this composition range. With these data, the ferroelectric phase diagram between PZ and PCoN has been established. © 2008 Trans Tech Publications, Switzerland.
format Book Series
author W. Banlue
R. Muanghlua
W. C. Vittayakorn
N. Vittayakom
author_facet W. Banlue
R. Muanghlua
W. C. Vittayakorn
N. Vittayakom
author_sort W. Banlue
title Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
title_short Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
title_full Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
title_fullStr Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
title_full_unstemmed Synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)PbZrO3-xPb(Co1/3Nb 2/3)O3 solid solution system
title_sort synthesis, crystal structures, phase transition characterization and thermal properties of the (1-x)pbzro3-xpb(co1/3nb 2/3)o3 solid solution system
publishDate 2018
url https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=62949103017&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/60397
_version_ 1681425428266352640

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