Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer
A pillared-layered coordination polymer of formula Co(H2NCH2CH2NH2)SO4(1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is composed of regularly alternating CoO4N2octahedra and SO...
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th-cmuir.6653943832-605012018-09-10T03:44:00Z Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer Sanchai Lauchan Timothy J. Prior Santi Meansiri Apinpus Rujiwatra Materials Science A pillared-layered coordination polymer of formula Co(H2NCH2CH2NH2)SO4(1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is composed of regularly alternating CoO4N2octahedra and SO4tetrahedra, with ethylenediamine pillars connecting the adjacent sheets. The coordinate covalent and hydrogen bonds have been revealed to exhibit an important role in the organization of the structure. The compound is found to be thermally stable up to, and above, 573 K and exhibits paramagnetic behavior at room temperature. © 2008 Springer Science+Business Media, LLC. 2018-09-10T03:44:00Z 2018-09-10T03:44:00Z 2008-09-01 Journal 15741451 15741443 2-s2.0-46649113934 10.1007/s10904-008-9208-x https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=46649113934&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/60501 |
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Materials Science Sanchai Lauchan Timothy J. Prior Santi Meansiri Apinpus Rujiwatra Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer |
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A pillared-layered coordination polymer of formula Co(H2NCH2CH2NH2)SO4(1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is composed of regularly alternating CoO4N2octahedra and SO4tetrahedra, with ethylenediamine pillars connecting the adjacent sheets. The coordinate covalent and hydrogen bonds have been revealed to exhibit an important role in the organization of the structure. The compound is found to be thermally stable up to, and above, 573 K and exhibits paramagnetic behavior at room temperature. © 2008 Springer Science+Business Media, LLC. |
| format |
Journal |
| author |
Sanchai Lauchan Timothy J. Prior Santi Meansiri Apinpus Rujiwatra |
| author_facet |
Sanchai Lauchan Timothy J. Prior Santi Meansiri Apinpus Rujiwatra |
| author_sort |
Sanchai Lauchan |
| title |
Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer |
| title_short |
Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer |
| title_full |
Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer |
| title_fullStr |
Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer |
| title_full_unstemmed |
Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer |
| title_sort |
cobalt(ethylenediamine)sulfate: a pillared layered coordination polymer |
| publishDate |
2018 |
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https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=46649113934&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/60501 |
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