Characterization of MMoO4 (M = Ba, Sr and Ca) with different morphologies prepared using a cyclic microwave radiation
Scheelite molybdates (MMoO4, M = Ba, Sr and Ca) were successfully prepared by the reactions of M(NO3)2·2H2O and Na2MoO4·2H2O in propylene glycol and NaOH using a microwave radiation. The phases were detected using XRD and SAED. TEM analysis revealed the presence of micro-sized bi-pyramids with a squ...
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| Main Authors: | , , |
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| Format: | Journal |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=36448932718&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/60542 |
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| Institution: | Chiang Mai University |
| Summary: | Scheelite molybdates (MMoO4, M = Ba, Sr and Ca) were successfully prepared by the reactions of M(NO3)2·2H2O and Na2MoO4·2H2O in propylene glycol and NaOH using a microwave radiation. The phases were detected using XRD and SAED. TEM analysis revealed the presence of micro-sized bi-pyramids with a square base, nano-sized particles in clusters, and dispersed nano-sized particles for BaMoO4, SrMoO4and CaMoO4, respectively. Diffraction patterns of the bi-pyramids were simulated, and are in accord with the experimental results. Raman and FTIR spectra provide the evidence of scheelite structure with Mo-O stretching vibration in MoO42-tetrahedrons at 742-901 cm- 1. © 2007 Elsevier B.V. All rights reserved. |
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