Tris(ethyl-enediamine)cobalt(II) sulfate
The structure of the title compound, [Co(II)(C(2)H(8)N(2))(3)]SO(4), the cobalt example of [M(C(2)H(8)N(2))(3)]SO(4), is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethyl-enedi...
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Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
2014
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Online Access: | http://www.ncbi.nlm.nih.gov/pubmed/3502482 http://cmuir.cmu.ac.th/handle/6653943832/6065 |
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Institution: | Chiang Mai University |
Language: | English |
Summary: | The structure of the title compound, [Co(II)(C(2)H(8)N(2))(3)]SO(4), the cobalt example of [M(C(2)H(8)N(2))(3)]SO(4), is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethyl-enediamine mol-ecules generated from half of the ethyl-enediamine mol-ecule in the asymmetric unit. The O atoms of the sulfate anion are disordered mostly over two crystallographic sites. The third disorder site of O (site symmetry 3) has a site occupancy approaching zero. The H atoms of the ethyl-enediamine mol-ecules inter-act with the sulfate anions via inter-molecular N-H⋯O hydrogen-bonding inter-actions. |
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