Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films

Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films

The synthesis, layer-by-layer deposition, and electro-copolymerization of precursor polyelectrolyte multilayer ultrathin films with thiophene and carbazole electroactive groups are described. The interest is in observing an electrochemical cross-linking approach towards a highly ordered ultrathin fi...

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Main Authors: Paralee Waenkaew, Prasad Taranekar, Sukon Phanichphant, Rigoberto C. Advincula
Format: Journal
Published: 2018
Subjects:
Materials Science
Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34548020290&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/61184
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Institution: Chiang Mai University
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spelling th-cmuir.6653943832-611842018-09-10T04:06:14Z Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films Paralee Waenkaew Prasad Taranekar Sukon Phanichphant Rigoberto C. Advincula Materials Science The synthesis, layer-by-layer deposition, and electro-copolymerization of precursor polyelectrolyte multilayer ultrathin films with thiophene and carbazole electroactive groups are described. The interest is in observing an electrochemical cross-linking approach towards a highly ordered ultrathin film that contains two types of monomers to result in possible layer-limited homo-and copolymerization. A uniform linear growth with alternate deposition of the polyelectrolytes is observed. The multilayer films were then electrochemically polymerized anodically by cyclic voltammetry (CV), which results in copolymerization between two different electroactive groups. Cross-linking of the layers was verified by CV and spectroelectrochemistry data with very good linear electro-copolymerizability. © 2007 WILEY-VCH Verlag GmbH & Co. KGaA. 2018-09-10T04:06:14Z 2018-09-10T04:06:14Z 2007-08-01 Journal 15213927 10221336 2-s2.0-34548020290 10.1002/marc.200700217 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34548020290&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/61184
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
topic Materials Science
spellingShingle Materials Science
Paralee Waenkaew
Prasad Taranekar
Sukon Phanichphant
Rigoberto C. Advincula
Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
description The synthesis, layer-by-layer deposition, and electro-copolymerization of precursor polyelectrolyte multilayer ultrathin films with thiophene and carbazole electroactive groups are described. The interest is in observing an electrochemical cross-linking approach towards a highly ordered ultrathin film that contains two types of monomers to result in possible layer-limited homo-and copolymerization. A uniform linear growth with alternate deposition of the polyelectrolytes is observed. The multilayer films were then electrochemically polymerized anodically by cyclic voltammetry (CV), which results in copolymerization between two different electroactive groups. Cross-linking of the layers was verified by CV and spectroelectrochemistry data with very good linear electro-copolymerizability. © 2007 WILEY-VCH Verlag GmbH & Co. KGaA.
format Journal
author Paralee Waenkaew
Prasad Taranekar
Sukon Phanichphant
Rigoberto C. Advincula
author_facet Paralee Waenkaew
Prasad Taranekar
Sukon Phanichphant
Rigoberto C. Advincula
author_sort Paralee Waenkaew
title Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
title_short Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
title_full Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
title_fullStr Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
title_full_unstemmed Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
title_sort electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films
publishDate 2018
url https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34548020290&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/61184
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