Metallosurfactants: Interfaces and micelles
Incorporating a metal cation as an integral component of the headgroup of a surfactant - a metallosurfactant - offers a route to concentrate these ions and their associated functionality at interfaces. To reduce the lability of the metal, various chelating or macrocyclic ligands may be employed lead...
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th-cmuir.6653943832-615602018-09-11T09:01:54Z Metallosurfactants: Interfaces and micelles P. C. Griffiths I. A. Fallis T. Chuenpratoom R. Watanesk Chemical Engineering Chemistry Physics and Astronomy Incorporating a metal cation as an integral component of the headgroup of a surfactant - a metallosurfactant - offers a route to concentrate these ions and their associated functionality at interfaces. To reduce the lability of the metal, various chelating or macrocyclic ligands may be employed leading to a family of homologous series of related metallosurfactants with a structural diversity that is arguably broader than is inherently possible with conventional surfactants. This review discusses the small number of key papers that are quantifying the physico-chemical properties of metallosurfactants and highlights their "classical" as well as "non-classical" surfactant behaviour, providing an insight into the structure of micelles and films formed from these novel materials. © 2006 Elsevier B.V. All rights reserved. 2018-09-11T08:55:06Z 2018-09-11T08:55:06Z 2006-09-25 Journal 00018686 2-s2.0-33748184382 10.1016/j.cis.2006.06.010 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33748184382&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/61560 |
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Chemical Engineering Chemistry Physics and Astronomy P. C. Griffiths I. A. Fallis T. Chuenpratoom R. Watanesk Metallosurfactants: Interfaces and micelles |
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Incorporating a metal cation as an integral component of the headgroup of a surfactant - a metallosurfactant - offers a route to concentrate these ions and their associated functionality at interfaces. To reduce the lability of the metal, various chelating or macrocyclic ligands may be employed leading to a family of homologous series of related metallosurfactants with a structural diversity that is arguably broader than is inherently possible with conventional surfactants. This review discusses the small number of key papers that are quantifying the physico-chemical properties of metallosurfactants and highlights their "classical" as well as "non-classical" surfactant behaviour, providing an insight into the structure of micelles and films formed from these novel materials. © 2006 Elsevier B.V. All rights reserved. |
format |
Journal |
author |
P. C. Griffiths I. A. Fallis T. Chuenpratoom R. Watanesk |
author_facet |
P. C. Griffiths I. A. Fallis T. Chuenpratoom R. Watanesk |
author_sort |
P. C. Griffiths |
title |
Metallosurfactants: Interfaces and micelles |
title_short |
Metallosurfactants: Interfaces and micelles |
title_full |
Metallosurfactants: Interfaces and micelles |
title_fullStr |
Metallosurfactants: Interfaces and micelles |
title_full_unstemmed |
Metallosurfactants: Interfaces and micelles |
title_sort |
metallosurfactants: interfaces and micelles |
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2018 |
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https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33748184382&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/61560 |
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