Simple spectrophotometric flow injection system with an in-valve minicolumn for enhancement during the determination of chromium(III) using EDTA

• Main Authors: Somchai Lapanantnoppakhun, Supharphorn Kasuwas, Lucksagoon Ganranoo, Jaroon Jakmunee, Kate Grudpan
• Format: Journal
• Published: 2018
• Subjects: Chemistry
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=30744455508&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/61593
• Institution: Chiang Mai University

A simple spectrophotometric flow injection (FI) procedure for the determination of Cr(III) using ethylenediaminetetraacetic acid (EDTA) was developed. An FI system with a column packed with Amberlite IR-120(H) was employed for sample pretreatment. This leads to the possibility of a single standard calibration. A linear calibration in a range of 10-27 mu;g Cr(III) was obtained with a detection limit of 1 μg Cr(III) and RSD of 2% (18 μg Cr(III), n = 12). The proposed procedure was applied for determination of Cr(III) in leachate and dietary supplement samples. The results agreed with those obtained by the standard methods. 2006 © The Japan Society for Analytical Chemistry.