Effects of alumina surrounding in sintering process on ZnO-Bi<inf>2</inf>O<inf>3</inf>varistors doped with CoO

Nonlinear current-voltage properties of zinc oxide-bismuth oxide varistors doped with cobalt oxide were investigated. The composition of ZnO doped with 0.5 mol% Bi2O3and 0.75 mol%CoO was prepared and sintered in two different surroundings, zinc oxide-bismuth oxide-cobalt oxide powder and alumina pow...

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Bibliographic Details
Main Authors: W. Onreabroy, T. Tunkasiri, N. Sirikulrat
Format: Journal
Published: 2018
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Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=9644272421&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/62217
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Institution: Chiang Mai University
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Summary:Nonlinear current-voltage properties of zinc oxide-bismuth oxide varistors doped with cobalt oxide were investigated. The composition of ZnO doped with 0.5 mol% Bi2O3and 0.75 mol%CoO was prepared and sintered in two different surroundings, zinc oxide-bismuth oxide-cobalt oxide powder and alumina powder. Microstructures and element tracing were studied using scanning electron microscopy with X-ray microanalysis, electron probe microanalysis and X-ray diffraction. Results clearly showed that the alumina surrounding led to bismuth loss from the green body and degraded the nonlinear property of varistors. At sintering temperatures higher than 1150°C, the alumina-surrounding sintered specimens became ohmic and the electrical resistivity of 200 Ω cm was found in the specimen sintered at 1200°C. © 2004 Elsevier B.V. All rights reserved.