Tris(ethylenediamine)cobalt(II) sulfate
The structure of the title compound, [CoII(C2H 8N2)3]SO4, the cobalt example of [M(C2H8N2)3]SO4, is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethyl-enediamine mol-ecules gene...
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2014
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th-cmuir.6653943832-62522014-08-30T03:24:01Z Tris(ethylenediamine)cobalt(II) sulfate Yotnoi B. Seeharaj A. Chimupala Y. Rujiwatra A. The structure of the title compound, [CoII(C2H 8N2)3]SO4, the cobalt example of [M(C2H8N2)3]SO4, is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethyl-enediamine mol-ecules generated from half of the ethyl-enediamine mol-ecule in the asymmetric unit. The O atoms of the sulfate anion are disordered mostly over two crystallographic sites. The third disorder site of O (site symmetry 3) has a site occupancy approaching zero. The H atoms of the ethyl-enediamine mol-ecules inter-act with the sulfate anions via inter-molecular N - H⋯O hydrogen-bonding inter-actions. 2014-08-30T03:24:01Z 2014-08-30T03:24:01Z 2010 Article 16005368 10.1107/S1600536810016168 http://www.scopus.com/inward/record.url?eid=2-s2.0-77953207177&partnerID=40&md5=12cd9b32bdd6c88a9929774d1a5b5c8c http://cmuir.cmu.ac.th/handle/6653943832/6252 English |
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English |
| description |
The structure of the title compound, [CoII(C2H 8N2)3]SO4, the cobalt example of [M(C2H8N2)3]SO4, is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethyl-enediamine mol-ecules generated from half of the ethyl-enediamine mol-ecule in the asymmetric unit. The O atoms of the sulfate anion are disordered mostly over two crystallographic sites. The third disorder site of O (site symmetry 3) has a site occupancy approaching zero. The H atoms of the ethyl-enediamine mol-ecules inter-act with the sulfate anions via inter-molecular N - H⋯O hydrogen-bonding inter-actions. |
| format |
Article |
| author |
Yotnoi B. Seeharaj A. Chimupala Y. Rujiwatra A. |
| spellingShingle |
Yotnoi B. Seeharaj A. Chimupala Y. Rujiwatra A. Tris(ethylenediamine)cobalt(II) sulfate |
| author_facet |
Yotnoi B. Seeharaj A. Chimupala Y. Rujiwatra A. |
| author_sort |
Yotnoi B. |
| title |
Tris(ethylenediamine)cobalt(II) sulfate |
| title_short |
Tris(ethylenediamine)cobalt(II) sulfate |
| title_full |
Tris(ethylenediamine)cobalt(II) sulfate |
| title_fullStr |
Tris(ethylenediamine)cobalt(II) sulfate |
| title_full_unstemmed |
Tris(ethylenediamine)cobalt(II) sulfate |
| title_sort |
tris(ethylenediamine)cobalt(ii) sulfate |
| publishDate |
2014 |
| url |
http://www.scopus.com/inward/record.url?eid=2-s2.0-77953207177&partnerID=40&md5=12cd9b32bdd6c88a9929774d1a5b5c8c http://cmuir.cmu.ac.th/handle/6653943832/6252 |
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1681420578842476544 |