Effect of NaOH concentration on sorption isotherm of carboxymethyl rice starch films and prediction models

Effect of NaOH concentration on the sorption isotherm of carboxymethyl rice starch (CMSr) films was investigated. Sorption isotherms are important for predicting moisture sorption properties of the films via moisture sorption empirical models. The moisture sorptions isotherm of CMSr films synthesize...

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Bibliographic Details
Main Authors: Rachtanapun P., Tongdeesoontorn W.
Format: Article
Language:English
Published: 2014
Online Access:http://www.scopus.com/inward/record.url?eid=2-s2.0-80051780260&partnerID=40&md5=d798bd0453783bf175bd43727a758885
http://cmuir.cmu.ac.th/handle/6653943832/634
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Institution: Chiang Mai University
Language: English
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Summary:Effect of NaOH concentration on the sorption isotherm of carboxymethyl rice starch (CMSr) films was investigated. Sorption isotherms are important for predicting moisture sorption properties of the films via moisture sorption empirical models. The moisture sorptions isotherm of CMSr films synthesized with different NaOH concentrations (0, 10, 20, 30, 40 and 50% w/v) were studied at various relative humidity (16, 35, 55 and 76% RH), at 25±1°C. The equilibrium moisture content of the films increased dramatically above aw = 0.6. Guggenheim-Anderson-de Boer (GAB), Brunauer-Emmett-Teller (BET) and Oswin sorption models were fitted to the experimental data. The results showed that the increase in NaOH concentration caused a decrease in the monolayer water content (M0) of the films. The GAB model was found to be the best-fit model for CMSr films at aw 0.1-0.76, 25±1°C.