Characterization of copper sulfide nanostructured spheres and nanotubes synthesized by microwave-assisted solvothermal method
Copper sulfide nanostructured spheres and nanotubes were successfully synthesized, using a microwave-assisted solvothermal method, by the decomposition of [Cu(CH3CSNH2)2]Cl2 complexes, formed by the reaction of CuCl2·2H2O and CH3CSNH2 in ethylene glycol at different pH values, and identified by CHNS...
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th-cmuir.6653943832-63582014-08-30T03:24:07Z Characterization of copper sulfide nanostructured spheres and nanotubes synthesized by microwave-assisted solvothermal method Thongtem T. Phuruangrat A. Thongtem S. Copper sulfide nanostructured spheres and nanotubes were successfully synthesized, using a microwave-assisted solvothermal method, by the decomposition of [Cu(CH3CSNH2)2]Cl2 complexes, formed by the reaction of CuCl2·2H2O and CH3CSNH2 in ethylene glycol at different pH values, and identified by CHNS/O and FTIR analyses. The decrease in bonding energy of N-H revealed the coordination of copper ions and thioacetamide molecules. It was specified that nitrogen atoms of thioacetamide molecules were used to form Cu-thioacetamide complexes. XRD, SEM, TEM and SAED analyses show that the products were hexagonal CuS spheres in an extremely low pH solution, and hexagonal CuS nanotubes at a pH 13. Their Raman spectra show sharp peaks at 473 cm- 1, identified as the S-S stretching mode of S2 ions at the 4e sites. © 2009 Elsevier B.V. All rights reserved. 2014-08-30T03:24:07Z 2014-08-30T03:24:07Z 2010 Article 0167577X 10.1016/j.matlet.2009.10.021 MLETD http://www.scopus.com/inward/record.url?eid=2-s2.0-70449536385&partnerID=40&md5=642a38104e0130abdff6597cb1520e31 http://cmuir.cmu.ac.th/handle/6653943832/6358 English |
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Copper sulfide nanostructured spheres and nanotubes were successfully synthesized, using a microwave-assisted solvothermal method, by the decomposition of [Cu(CH3CSNH2)2]Cl2 complexes, formed by the reaction of CuCl2·2H2O and CH3CSNH2 in ethylene glycol at different pH values, and identified by CHNS/O and FTIR analyses. The decrease in bonding energy of N-H revealed the coordination of copper ions and thioacetamide molecules. It was specified that nitrogen atoms of thioacetamide molecules were used to form Cu-thioacetamide complexes. XRD, SEM, TEM and SAED analyses show that the products were hexagonal CuS spheres in an extremely low pH solution, and hexagonal CuS nanotubes at a pH 13. Their Raman spectra show sharp peaks at 473 cm- 1, identified as the S-S stretching mode of S2 ions at the 4e sites. © 2009 Elsevier B.V. All rights reserved. |
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Thongtem T. Phuruangrat A. Thongtem S. |
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Thongtem T. Phuruangrat A. Thongtem S. Characterization of copper sulfide nanostructured spheres and nanotubes synthesized by microwave-assisted solvothermal method |
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Thongtem T. Phuruangrat A. Thongtem S. |
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Thongtem T. |
title |
Characterization of copper sulfide nanostructured spheres and nanotubes synthesized by microwave-assisted solvothermal method |
title_short |
Characterization of copper sulfide nanostructured spheres and nanotubes synthesized by microwave-assisted solvothermal method |
title_full |
Characterization of copper sulfide nanostructured spheres and nanotubes synthesized by microwave-assisted solvothermal method |
title_fullStr |
Characterization of copper sulfide nanostructured spheres and nanotubes synthesized by microwave-assisted solvothermal method |
title_full_unstemmed |
Characterization of copper sulfide nanostructured spheres and nanotubes synthesized by microwave-assisted solvothermal method |
title_sort |
characterization of copper sulfide nanostructured spheres and nanotubes synthesized by microwave-assisted solvothermal method |
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2014 |
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http://www.scopus.com/inward/record.url?eid=2-s2.0-70449536385&partnerID=40&md5=642a38104e0130abdff6597cb1520e31 http://cmuir.cmu.ac.th/handle/6653943832/6358 |
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