Synthesis, Characterization, and Crystal Structure Determination of Mercury(II) Complex Containing 2-(Aminomethyl)pyridine
The new complex of [Hg(2-AMPy)I2] (1) was synthesized from the reaction of HgI2 with 2-(aminomethyl)pyridine (2-AMPy) in methanolic solution. Suitable crystals of 1 for diffraction experiment were obtained by slow evaporation from DMSO. Resulted complex was characterized by spectral methods (IR and...
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Science Faculty of Chiang Mai University
2019
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| Online Access: | http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=8760 http://cmuir.cmu.ac.th/jspui/handle/6653943832/64036 |
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th-cmuir.6653943832-640362019-05-07T09:59:44Z Synthesis, Characterization, and Crystal Structure Determination of Mercury(II) Complex Containing 2-(Aminomethyl)pyridine Sadif A Shirvan Fereydoon Khazali Sara Haydari Dezfuli Ali Borsalani The new complex of [Hg(2-AMPy)I2] (1) was synthesized from the reaction of HgI2 with 2-(aminomethyl)pyridine (2-AMPy) in methanolic solution. Suitable crystals of 1 for diffraction experiment were obtained by slow evaporation from DMSO. Resulted complex was characterized by spectral methods (IR and 1H NMR), elemental analysis, thermal analysis and single crystal X-ray diffraction method. In this compound, four coordinated arrangement of the Hg(II) center can be described as a seesaw geometry with the four-coordinate geometry index, t4, of 0.77. 2019-05-07T09:59:44Z 2019-05-07T09:59:44Z 2018 บทความวารสาร 0125-2526 http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=8760 http://cmuir.cmu.ac.th/jspui/handle/6653943832/64036 Eng Science Faculty of Chiang Mai University |
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Thailand |
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English |
| description |
The new complex of [Hg(2-AMPy)I2] (1) was synthesized from the reaction of HgI2 with 2-(aminomethyl)pyridine (2-AMPy) in methanolic solution. Suitable crystals of 1 for diffraction experiment were obtained by slow evaporation from DMSO. Resulted complex was characterized by spectral methods (IR and 1H NMR), elemental analysis, thermal analysis and single crystal X-ray diffraction method. In this compound, four coordinated arrangement of the Hg(II) center can be described as a seesaw geometry with the four-coordinate geometry index, t4, of 0.77. |
| format |
บทความวารสาร |
| author |
Sadif A Shirvan Fereydoon Khazali Sara Haydari Dezfuli Ali Borsalani |
| spellingShingle |
Sadif A Shirvan Fereydoon Khazali Sara Haydari Dezfuli Ali Borsalani Synthesis, Characterization, and Crystal Structure Determination of Mercury(II) Complex Containing 2-(Aminomethyl)pyridine |
| author_facet |
Sadif A Shirvan Fereydoon Khazali Sara Haydari Dezfuli Ali Borsalani |
| author_sort |
Sadif A Shirvan |
| title |
Synthesis, Characterization, and Crystal Structure Determination of Mercury(II) Complex Containing 2-(Aminomethyl)pyridine |
| title_short |
Synthesis, Characterization, and Crystal Structure Determination of Mercury(II) Complex Containing 2-(Aminomethyl)pyridine |
| title_full |
Synthesis, Characterization, and Crystal Structure Determination of Mercury(II) Complex Containing 2-(Aminomethyl)pyridine |
| title_fullStr |
Synthesis, Characterization, and Crystal Structure Determination of Mercury(II) Complex Containing 2-(Aminomethyl)pyridine |
| title_full_unstemmed |
Synthesis, Characterization, and Crystal Structure Determination of Mercury(II) Complex Containing 2-(Aminomethyl)pyridine |
| title_sort |
synthesis, characterization, and crystal structure determination of mercury(ii) complex containing 2-(aminomethyl)pyridine |
| publisher |
Science Faculty of Chiang Mai University |
| publishDate |
2019 |
| url |
http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=8760 http://cmuir.cmu.ac.th/jspui/handle/6653943832/64036 |
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1681426006659825664 |