Synthesis of Poly(rac-lactide) Using Tri-n-Butyltin(IV) n-Butoxide as Initiator: The Investigation on Stereochemistry and Polymerization Mechanism

• المؤلفون الرئيسيون: Wanich Limwanich, Puttinan Meepowpan, Nawee Kungwan, Winita Punyodom
• التنسيق: บทความวารสาร
• اللغة: English
• منشور في: Science Faculty of Chiang Mai University 2019
• الوصول للمادة أونلاين: http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=9401; http://cmuir.cmu.ac.th/jspui/handle/6653943832/64180
• المؤسسة: Chiang Mai University

The ring-opening polymerization (ROP) of racemic-lactide (rac-LA) initiated by the synthesized tri-n-butyltin(IV) n-butoxide (nBu3SnOnBu) was investigated for first time by proton- and carbon-13 nuclear magnetic resonance spectroscopy (1H- and 13C-NMR). The polymerization of rac-LA with nBu3SnOnBu a...