Dielectric aging behavior in A-site hybrid-doped BaTiO3 ceramics
Hybrid-doped ferroelectric ceramics have recently been of great interest. Their electrical properties; however, remained mysterious, particularly the aging behavior. Therefore, the dielectric aging characteristics of the A-site hybrid-doped Na1+/Sm3+ BaTiO3 perovskite ceramics were investigated in t...
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Main Authors: | , , , , , , |
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Format: | Conference or Workshop Item |
Language: | English |
Published: |
2014
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Online Access: | http://www.scopus.com/inward/record.url?eid=2-s2.0-80255136268&partnerID=40&md5=3a480ddf189fb904c355dd4eddb94178 http://cmuir.cmu.ac.th/handle/6653943832/6567 |
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Institution: | Chiang Mai University |
Language: | English |
Summary: | Hybrid-doped ferroelectric ceramics have recently been of great interest. Their electrical properties; however, remained mysterious, particularly the aging behavior. Therefore, the dielectric aging characteristics of the A-site hybrid-doped Na1+/Sm3+ BaTiO3 perovskite ceramics were investigated in this study. With the concentration of acceptor dopant (Na1+) fixed at 1 mol%, while that of the donor dopant (Sm3+) varied from 0.0 to 1.5 mol%, the hybrid-doped BaTiO 3 ceramics were prepared successfully by a conventional mixed-oxide method via vibro-milling technique. The results showed that the dielectric properties of all de-aged samples decreased noticeably with time. In all the samples with 0.5, 1.0 and 1.5 mol% Sm3+ obviously the aging of dielectric constant and dielectric loss did not follow the conventional logarithmic law. The stretched exponential decay was found to suitably represent the aging behavior of these A-site hybrid-doped BaTiO3 ceramics. A possibly cause of such behavior lies in the nature of relaxor-like behavior of these ceramics induced from a disruption of dipole ordering from Na 1+/Sm3+ substitution. © 2011 Elsevier B.V. All rights reserved. |
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