Lanthanide sulfate frameworks: Synthesis, structure, and optical properties

• Main Authors: Yotnoi B., Rujiwatra A., Reddy M.L.P., Sarma D., Natarajan S.
• Format: Article
• Language: English
• Published: 2014
• Online Access: http://www.scopus.com/inward/record.url?eid=2-s2.0-79953852767&partnerID=40&md5=f8bab28a8b8494c2ef7701dea5881a2f; http://cmuir.cmu.ac.th/handle/6653943832/6579
• Institution: Chiang Mai University

Layered lanthanide sulfate compounds with three different structures have been prepared and characterized. The compounds [C10H 10N2][La(SO4)2]·2H 2O (I), [C10H10N2][La(SO 4)2(H2O)2]2 (IIa), [C10H10N2][Pr(SO4) 2(H2O)2]2 (IIb), [C 10H10N2][Nd2(SO4) 4(H2O)2]2 (IIIa), [C 10H10N2][Sm2(SO4) 4(H2O)2]2 (IIIb), and [C 10H10N2][Eu2(SO4) 4(H2O)2]2 (IIIc) have anionic lanthanide sulfate layers separated by protonated bipyridine molecules. The layers are formed by the connectivity between the lanthanide polyhedra and sulfate tetrahedra. The formation of a two-dimensional La-O-La layer (Ia), Pr-O-Pr chains (IIb), and a tetramer cluster (IIIa) is noteworthy. The compounds exhibit honeycomb (I), square (IIa, IIb), and honeycomb (IIIa-IIIc) net arrangements, when the connectivity between the lanthanide ions is considered. Optical studies indicate the observation of characteristic metal-centered emission at room temperature. The Nd compound (IIIa) exhibits a two-photon upconversion behavior.(Figure Presented) © 2011 American Chemical Society.