Gallocyanine as An Efficient Catalyst for Synthesis of Benzimidazoles in Aqueous Ethanol

The benzimidazole derivatives have been obtained catalyzed by gallocyanine. A wide range of aromatic aldehydes easily undergo condensation with substituted o-phenylendiamine under mild conditions to afford the target molecules in excellent yields. The products were obtained in 80–93% yields in 30–80...

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Main Authors: Min Zhang, Chunshu Liao, Zhenyuan Lin, Bin Li, Yibiao Li, Lu Chen
Language:English
Published: Science Faculty of Chiang Mai University 2019
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Online Access:http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=10220
http://cmuir.cmu.ac.th/jspui/handle/6653943832/66050
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spelling th-cmuir.6653943832-660502019-08-21T09:18:20Z Gallocyanine as An Efficient Catalyst for Synthesis of Benzimidazoles in Aqueous Ethanol Min Zhang Chunshu Liao Zhenyuan Lin Bin Li Yibiao Li Lu Chen benzimidazole gallocyanine aromatic aldehyde heterocycles The benzimidazole derivatives have been obtained catalyzed by gallocyanine. A wide range of aromatic aldehydes easily undergo condensation with substituted o-phenylendiamine under mild conditions to afford the target molecules in excellent yields. The products were obtained in 80–93% yields in 30–80 min. The method has several advantages such as use of green solvent, easy work-up, excellent yield and avoiding use of inconvenient preparation of catalyst. Meanwhile, the catalyst gallocyanine is a kind of inexpensive catalyst, which might be applied to broad green catalytic system. 2019-08-21T09:18:20Z 2019-08-21T09:18:20Z 2019 Chiang Mai Journal of Science 46, 4 (July 2019), 727 - 732 0125-2526 http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=10220 http://cmuir.cmu.ac.th/jspui/handle/6653943832/66050 Eng Science Faculty of Chiang Mai University
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
language English
topic benzimidazole
gallocyanine
aromatic aldehyde
heterocycles
spellingShingle benzimidazole
gallocyanine
aromatic aldehyde
heterocycles
Min Zhang
Chunshu Liao
Zhenyuan Lin
Bin Li
Yibiao Li
Lu Chen
Gallocyanine as An Efficient Catalyst for Synthesis of Benzimidazoles in Aqueous Ethanol
description The benzimidazole derivatives have been obtained catalyzed by gallocyanine. A wide range of aromatic aldehydes easily undergo condensation with substituted o-phenylendiamine under mild conditions to afford the target molecules in excellent yields. The products were obtained in 80–93% yields in 30–80 min. The method has several advantages such as use of green solvent, easy work-up, excellent yield and avoiding use of inconvenient preparation of catalyst. Meanwhile, the catalyst gallocyanine is a kind of inexpensive catalyst, which might be applied to broad green catalytic system.
author Min Zhang
Chunshu Liao
Zhenyuan Lin
Bin Li
Yibiao Li
Lu Chen
author_facet Min Zhang
Chunshu Liao
Zhenyuan Lin
Bin Li
Yibiao Li
Lu Chen
author_sort Min Zhang
title Gallocyanine as An Efficient Catalyst for Synthesis of Benzimidazoles in Aqueous Ethanol
title_short Gallocyanine as An Efficient Catalyst for Synthesis of Benzimidazoles in Aqueous Ethanol
title_full Gallocyanine as An Efficient Catalyst for Synthesis of Benzimidazoles in Aqueous Ethanol
title_fullStr Gallocyanine as An Efficient Catalyst for Synthesis of Benzimidazoles in Aqueous Ethanol
title_full_unstemmed Gallocyanine as An Efficient Catalyst for Synthesis of Benzimidazoles in Aqueous Ethanol
title_sort gallocyanine as an efficient catalyst for synthesis of benzimidazoles in aqueous ethanol
publisher Science Faculty of Chiang Mai University
publishDate 2019
url http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=10220
http://cmuir.cmu.ac.th/jspui/handle/6653943832/66050
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