Unexpected Formation of Copper Dimethylglyoxime Dimer From the Reaction of Cuprous Chloride and Tetradentate Buthylene-Bridged Diiminedioxime Ligand
A reaction of a ligand 3,3´-(1,4-butanediyldinitrilo)bis(2-butanone)dioxime (BnH2) and CuCl yield green [Cu(H2dmg)Cl(μ-Cl)]2,1. The dimethylglyoxime (H2dmg) and CuIIions in 1 were in situ produced during the course of reaction and formed doubly chloro-bridged Cu(II) dimers. The geometry around copp...
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| Main Authors: | , , , |
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| Language: | English |
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Science Faculty of Chiang Mai University
2019
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| Subjects: | |
| Online Access: | http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=5956 http://cmuir.cmu.ac.th/jspui/handle/6653943832/66143 |
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| Institution: | Chiang Mai University |
| Language: | English |
| Summary: | A reaction of a ligand 3,3´-(1,4-butanediyldinitrilo)bis(2-butanone)dioxime (BnH2) and CuCl yield green [Cu(H2dmg)Cl(μ-Cl)]2,1. The dimethylglyoxime (H2dmg) and CuIIions in 1 were in situ produced during the course of reaction and formed doubly chloro-bridged Cu(II) dimers. The geometry around copper ion is distorted square pyramidal. The weak intermolecular hydrogen bonds are observed in 1 giving 1D structure. The existence of two O–O distances of O2–O1= 2.922 Ǻ and O4–O3= 2.910 Ǻ indicates that these weak intermolecular hydrogen bonds are not equivalent. Hence doublet of the O-H stretching at 3302 and 3216 cm-1 are observed. |
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