Crystal growth and characterisation of a unique trinuclear VIV/VV complex

• Main Authors: Chimupala Y., Phonsri W., Prior T.J., Rujiwatra A.
• Format: Article
• Language: English
• Published: 2014
• Online Access: http://www.scopus.com/inward/record.url?eid=2-s2.0-79953035486&partnerID=40&md5=ae51d7feaf042dceafb2723b2df6d621; http://cmuir.cmu.ac.th/handle/6653943832/6630
• Institution: Chiang Mai University

Single crystals of a mixed-valence trinuclear cluster of formula [V2VVIVO5(C12H8N2)3(SO4)2(H2O)3].6H2O were grown by layer diffusion technique and characterised by single-crystal X-ray diffraction; P21/c, a = 20.5448(11) Å, b = 11.7647(9) Å, c = 18.1871(9) Å, β = 92.64(0)°, V = 4391.22 (93) Å3, R =...