Isoconversional kinetic analysis of ring-opening polymerization of ε-caprolactone: Steric influence of titanium(IV) alkoxides as initiators

• Main Authors: Meelua W., Molloy R., Meepowpan P., Punyodom W.
• 格式: Article
• 語言: English
• 出版: 2014
• 在線閱讀: http://www.scopus.com/inward/record.url?eid=2-s2.0-84857126811&partnerID=40&md5=ceb63b740e911d9c1a9e399dff86c9eb; http://cmuir.cmu.ac.th/handle/6653943832/6841
• 機構: Chiang Mai University

Four titanium(IV) alkoxides, namely: Ti(IV) npropoxide (1), Ti(IV) n-butoxide (2), Ti(IV) tert-butoxide (3), and Ti(IV) 2-ethylhexoxide (4), have been used as initiators in the bulk ring-opening polymerization (ROP) of ε-caprolactone (ε-CL). The influence of the alkoxide group on the course of the R...