Effect of Calcination Temperature of Musa sapientum Linn Peels as a Novel Biobased Heterogeneous Catalyst for Soybean Oil-derived Fatty Acid Methyl Ester Formation
Chiang Mai Journal of Science
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Faculty of Science, Chiang Mai University
2020
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| Online Access: | https://epg.science.cmu.ac.th/ejournal/dl.php?journal_id=10919 http://cmuir.cmu.ac.th/jspui/handle/6653943832/68747 |
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th-cmuir.6653943832-687472020-06-10T07:12:28Z Effect of Calcination Temperature of Musa sapientum Linn Peels as a Novel Biobased Heterogeneous Catalyst for Soybean Oil-derived Fatty Acid Methyl Ester Formation Jakkrapong Jitjamnong Chachchaya Thunyaratchatanon Apanee Luengnaruemitchai Napaphat Kongrit Naparat Kasetsomboon Narinphop Chuaykarn Nonlapan Khantikulanon Musa sapientum Linn peels biodiesel transesterification heterogeneous catalyst catalyst reusability Chiang Mai Journal of Science In the present study, a novel solid base catalyst derived from desert banana (Musa sapientum Linn) peels was used as a catalyst for biodiesel production. The catalyst was calcined at several temperatures between 550–650 °C under atmosphere pressure for 4 h. The composition, structure and texture of the calcined banana peel (CBP) catalysts were characterized by X-ray diffraction, thermogravimetric analysis, scanning electron microscopy with energy dispersive spectroscopy, X-ray fluorescence spectrophotometry, and Fourier-transform infrared spectroscopy analyses. The fatty acid profile of the feed soybean oil and the fatty acid methyl ester (FAME) product composition was analyzed using gas chromatography with flame ionization detection. The prepared catalysts were then applied for the catalytic transesterification of soybean oil with methanol under microwave-assisted heating to form FAME. The effect of the calcination temperature in the catalyst preparation, the catalyst loading level, reaction time, methanol: soybean oil molar ratio and catalyst reusability on the FAME yield were determined by univariate analysis. The CBP catalyst synthesized at 600 °C exhibited the highest catalytic activity, since the calcined ash was rich in K, P, Ca and Mg which formed a basic heterogenous catalyst at this calcination temperature. At the determined optimal reaction condition (1 wt.% catalyst loading level, 12:1 molar ratio of methanol: soybean oil, and a 2 min of reaction time under 300 W microwave irradiation) a FAME yield of 99.3% was obtained. Furthermore, the catalyst showed a good reusability with a biodiesel yield of more than 80.7% after four uses. 2020-06-10T07:12:28Z 2020-06-10T07:12:28Z 2020 Chiang Mai Journal of Science 47,3 (May 2020), p.484-498 2465-3845 https://epg.science.cmu.ac.th/ejournal/dl.php?journal_id=10919 http://cmuir.cmu.ac.th/jspui/handle/6653943832/68747 Eng Faculty of Science, Chiang Mai University |
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Chiang Mai University Library |
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Asia |
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CMU Intellectual Repository |
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English |
| topic |
Musa sapientum Linn peels biodiesel transesterification heterogeneous catalyst catalyst reusability |
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Musa sapientum Linn peels biodiesel transesterification heterogeneous catalyst catalyst reusability Jakkrapong Jitjamnong Chachchaya Thunyaratchatanon Apanee Luengnaruemitchai Napaphat Kongrit Naparat Kasetsomboon Narinphop Chuaykarn Nonlapan Khantikulanon Effect of Calcination Temperature of Musa sapientum Linn Peels as a Novel Biobased Heterogeneous Catalyst for Soybean Oil-derived Fatty Acid Methyl Ester Formation |
| description |
Chiang Mai Journal of Science |
| author |
Jakkrapong Jitjamnong Chachchaya Thunyaratchatanon Apanee Luengnaruemitchai Napaphat Kongrit Naparat Kasetsomboon Narinphop Chuaykarn Nonlapan Khantikulanon |
| author_facet |
Jakkrapong Jitjamnong Chachchaya Thunyaratchatanon Apanee Luengnaruemitchai Napaphat Kongrit Naparat Kasetsomboon Narinphop Chuaykarn Nonlapan Khantikulanon |
| author_sort |
Jakkrapong Jitjamnong |
| title |
Effect of Calcination Temperature of Musa sapientum Linn Peels as a Novel Biobased Heterogeneous Catalyst for Soybean Oil-derived Fatty Acid Methyl Ester Formation |
| title_short |
Effect of Calcination Temperature of Musa sapientum Linn Peels as a Novel Biobased Heterogeneous Catalyst for Soybean Oil-derived Fatty Acid Methyl Ester Formation |
| title_full |
Effect of Calcination Temperature of Musa sapientum Linn Peels as a Novel Biobased Heterogeneous Catalyst for Soybean Oil-derived Fatty Acid Methyl Ester Formation |
| title_fullStr |
Effect of Calcination Temperature of Musa sapientum Linn Peels as a Novel Biobased Heterogeneous Catalyst for Soybean Oil-derived Fatty Acid Methyl Ester Formation |
| title_full_unstemmed |
Effect of Calcination Temperature of Musa sapientum Linn Peels as a Novel Biobased Heterogeneous Catalyst for Soybean Oil-derived Fatty Acid Methyl Ester Formation |
| title_sort |
effect of calcination temperature of musa sapientum linn peels as a novel biobased heterogeneous catalyst for soybean oil-derived fatty acid methyl ester formation |
| publisher |
Faculty of Science, Chiang Mai University |
| publishDate |
2020 |
| url |
https://epg.science.cmu.ac.th/ejournal/dl.php?journal_id=10919 http://cmuir.cmu.ac.th/jspui/handle/6653943832/68747 |
| _version_ |
1681752688164864000 |