Structural and magnetic properties of SiO 2-CaO-Na 2O-P 2O 5 containing BaO-Fe 2O 3 glass-ceramics
The incorporation method was employed to produce bioactive glass-ceramics from the BaFe 12O 19-SiO 2-CaO-Na 2O-P 2O 5 glass system. The ferrimagnetic BaFe 12O 19 was first prepared using a simple mixed oxide method, where the oxide precursors of 45S5 bioglass were initially mixed and then melted to...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
2014
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| Online Access: | http://www.scopus.com/inward/record.url?eid=2-s2.0-84867305594&partnerID=40&md5=7f2fca69fc2108bbadf35b1278450ba8 http://cmuir.cmu.ac.th/handle/6653943832/6892 |
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| Institution: | Chiang Mai University |
| Language: | English |
| Summary: | The incorporation method was employed to produce bioactive glass-ceramics from the BaFe 12O 19-SiO 2-CaO-Na 2O-P 2O 5 glass system. The ferrimagnetic BaFe 12O 19 was first prepared using a simple mixed oxide method, where the oxide precursors of 45S5 bioglass were initially mixed and then melted to form glass. The devitrification of Na 3Ca 6(PO 4) 5 and Fe 3O 4 was observed in all of the quenched glass samples. The glass samples were then subjected to a heat treatment schedule for further crystallization. It was found that the small traces of BaFe 12O 19 phases started to crystallize in high BF content samples of 20 and 40 wt%. These samples also exhibited good magnetic properties comparable to that of other magnetic glass-ceramics. The bioactivity of the BF glass-ceramics improved with increasing BF content as was evident by the formation of bone-like apatite layers on the surface of all of the glass-ceramics after soaking in SBF for 14 days. The results support the use of these bioactive glass-ceramics for hyperthermia treatment within the human body. © 2012 Elsevier B.V. All rights reserved. |
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