A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism

The Chiang Mai Journal of Science is an international English language peer-reviewed journal which is published in open access electronic format 6 times a year in January, March, May, July, September and November by the Faculty of Science, Chiang Mai University. Manuscripts in most areas of science...

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Main Authors: Wei Zhao, Youning Chen, Yuhong Li
Language:English
Published: Faculty of Science, Chiang Mai University 2020
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Online Access:https://epg.science.cmu.ac.th/ejournal/dl.php?journal_id=11202
http://cmuir.cmu.ac.th/jspui/handle/6653943832/69919
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spelling th-cmuir.6653943832-699192020-10-08T08:36:17Z A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism Wei Zhao Youning Chen Yuhong Li intercalated hydrotalcite adsorption heavy metal ion wastewater mechanism The Chiang Mai Journal of Science is an international English language peer-reviewed journal which is published in open access electronic format 6 times a year in January, March, May, July, September and November by the Faculty of Science, Chiang Mai University. Manuscripts in most areas of science are welcomed except in areas such as agriculture, engineering and medical science which are outside the scope of the Journal. Currently, we focus on manuscripts in biology, chemistry, physics, materials science and environmental science. Papers in mathematics statistics and computer science are also included but should be of an applied nature rather than purely theoretical. Manuscripts describing experiments on humans or animals are required to provide proof that all experiments have been carried out according to the ethical regulations of the respective institutional and/or governmental authorities and this should be clearly stated in the manuscript itself. The Editor reserves the right to reject manuscripts that fail to do so. In this paper, due to the anion exchange between the hydrotalcite layers, the functional nano-acrylic pillared hydrotalcite(AA-LDH) were prepared via back-mixing precipitation method with acrylic acid as the intercalation modifier. AA-LDH was characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The adsorption performance of AA-LDH for Pb(II), Cu(II), Zn(II) and Cd(II) was investigated. The maximum adsorption capacities of the AA-LDH were up to 4.35 mmol g-1 for Pb(II), 3.67 mmol g-1 for Cu(II), 1.75 mmol g-1 for Zn(II) and 1.23 mmol g-1 for Cd(II) at pH 5.0. The effects of pH on the adsorption suggested that the adsorption of metal ions was governed mainly by the chelation interaction. The adsorption isotherms of the three metal ions were best described by the Langmuir model, and their adsorption kinetics followed the pseudo second-order kinetic equation. The adsorption equilibrium was reached for the four ions within 3h. The adsorption of the three concerned metal ions was hardly affected by common coexisting ions such as Na(I), K(I), Ca(II) and Mg(II), whereas they were slightly decreased when Fe(II) coexisted in the solution, which illustrates the selective adsorption of Pb(II), Cu(II), Zn(II) and Cd(II) from wastewater. The AA-LDH has a good desorption rate and reusability. These findings suggest that the AA-LDH could be potentially applied to the efficient removal of heavy metal ions from waste water. 2020-10-08T08:36:17Z 2020-10-08T08:36:17Z 2020 Chiang Mai Journal of Science 47,5 (Sep 2020), p.1055-1067 2465-3845 https://epg.science.cmu.ac.th/ejournal/dl.php?journal_id=11202 http://cmuir.cmu.ac.th/jspui/handle/6653943832/69919 Eng Faculty of Science, Chiang Mai University
institution Chiang Mai University
building Chiang Mai University Library
continent Asia
country Thailand
Thailand
content_provider Chiang Mai University Library
collection CMU Intellectual Repository
language English
topic intercalated hydrotalcite
adsorption
heavy metal ion
wastewater
mechanism
spellingShingle intercalated hydrotalcite
adsorption
heavy metal ion
wastewater
mechanism
Wei Zhao
Youning Chen
Yuhong Li
A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism
description The Chiang Mai Journal of Science is an international English language peer-reviewed journal which is published in open access electronic format 6 times a year in January, March, May, July, September and November by the Faculty of Science, Chiang Mai University. Manuscripts in most areas of science are welcomed except in areas such as agriculture, engineering and medical science which are outside the scope of the Journal. Currently, we focus on manuscripts in biology, chemistry, physics, materials science and environmental science. Papers in mathematics statistics and computer science are also included but should be of an applied nature rather than purely theoretical. Manuscripts describing experiments on humans or animals are required to provide proof that all experiments have been carried out according to the ethical regulations of the respective institutional and/or governmental authorities and this should be clearly stated in the manuscript itself. The Editor reserves the right to reject manuscripts that fail to do so.
author Wei Zhao
Youning Chen
Yuhong Li
author_facet Wei Zhao
Youning Chen
Yuhong Li
author_sort Wei Zhao
title A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism
title_short A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism
title_full A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism
title_fullStr A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism
title_full_unstemmed A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism
title_sort novel acrylic intercalated hydrotalcite for the removal of heavy metal ions from aqueous solution: isotherm, kinetics, thermodynamics and mechanism
publisher Faculty of Science, Chiang Mai University
publishDate 2020
url https://epg.science.cmu.ac.th/ejournal/dl.php?journal_id=11202
http://cmuir.cmu.ac.th/jspui/handle/6653943832/69919
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