Application of the reaction class transition state theory to the kinetics of hydrogen abstraction reactions of alkanes by atomic chlorine

• المؤلفون الرئيسيون: Piansawan T., Kungwan N., Jungsuttiwong S.
• التنسيق: مقال
• اللغة: English
• منشور في: 2014
• الوصول للمادة أونلاين: http://www.scopus.com/inward/record.url?eid=2-s2.0-84875058175&partnerID=40&md5=325a1338ee40c192e66f7fc07f473351; http://cmuir.cmu.ac.th/handle/6653943832/7021

Kinetics of the hydrogen abstraction reaction of the class alkane + Cl → alkyl + HCl was studied using reaction class transition state theory (RC-TST) combined with linear energy relationships (LERs). The thermal rate coefficients for the reference reaction of ethane + Cl → ethyl + HCl, calculated b...